The accelerated carbonation with different pressure steaming conditions was used to process the steel slag, so the slag could turn into a primary cementitious product with carbonation activity. XRD, FTIR, TG, N2 absorption BET surface area analyzer and SEM were used to characterize the mineral and chemical compositions and microstructure of each sample before and after the carbonation. The results show that: the carbonation products with different morphologies are formed under different temperature conditions. The optimum temperature for the accelerated carbonation for processing the steel slag is selected to be 90 °C, which results in the compressive strength of 32.8 MPa. The BET specific surface area of the steel slag reduces after carbonation, the sample density increased after carbonation.
Many factors influence the wear of friction material performance such as formulation, manufacturing condition and operating regimes, and so on. In this paper, the wear rate variation has been modeled by means of artificial neural network, the network have been developed with all these relevant factors taking into consideration. 16 influence factors and wear rate selected as input and output respectly, 16 [10-8]2 1 is regarded as the best architecture of neural network, the Levenberg-Marquardt algorithm is used for training the network. The result shows that the model is valid to predict the wear property, as well as that it is useful for optimizing the formulation and manufacturing conditions, the relatively excellent combination of the ingredients and the appropriate manufacturing condition parameters can be obtained by this approach.
In this paper, we demonstrated a gold nanoparticle based two-photon photoluminescence (TPPL) assay for the detection of dopamine with the detection limit of 0.3 μM. Protonated dopamine molecules can bind bidentately to surface of gold atoms through the catechol group. The adsorption of dopamine displaces the stabilizing agent of citrate groups, and neutralizes the charge of solution, resulting in non-cross linking aggregation of Au NPs. Aggregation of Au NPs could induce significantly enhanced TPPL. Thus, a simple TPPL assay was designed. We have shown that when Au NPs solution was mixed with dopamine, TPPL intensity increased by about 47 times. The mechanism of sensing assay has been discussed. In addition, the TPPL assay was highly selective to dopamine and it can distinguish from uric acid, ascorbic acid and metal ions.
In this paper the waterproofness of desulfurization building gypsum had been improved by polyacrylamide(PAM) emulsion. The effect of dosage and molecular weight of PAM emulsion on the physical mechanical properties and waterproofness have been investigated and XRD, SEM have been employed to determine the phase compositions of the material. The results showed that softening coefficient of desulfurization building gypsum increased from 0.34 to 0.69, the compressive strength after soaking in water for 24 h increased from 4.9MPa to 6.1 MPa. The effect of PAM emulsion modification prepared by PAM with molecular 3 million weight of on desulfurization building gypsum are better than with molecular weight of 5 million. The effect mechanism of PAM on desulfurization building gypsum was that PAM reacts with the Ca2+ cations produced desulfurization building gypsum hydration to form the ionic compounds acting as a filler and reinforcement in the porosity of desulfurization building gypsum, and also PAM covered the surface of desulfurization building gypsum particles to prevent the crystallization of CaSO4.2H2O.
The property of raw kaolinite-coal-gangue is very stable, and reactivity of kaolinite-coal-gangue is enhanced by mechanical force. The SEM, XRD and IR were used to analyze mechanochemical changes during kaolinite-type-coal gangue grinding. The results showed that mechanical force plays a dominant role in the enhanced reactivity, by inducing dehydration reactions the lattice OH grouping decreased with the extension of grinding time. The separation of tetrahedral and octahedral layers combined with the increasing disorder of the kaolinite crystal structure, resulting in kaolinite-type-coal gangue particles become "loose" aggregates. Moreover, due to destroy to tight Si-O and Al-O bond, the mechanical force increases the solubility of SiO2 and Al2O3, which enhanced the reactivity of coal gangue.
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