An applied electric field can reversibly change the temperature of an electrocaloric material under adiabatic conditions, and the effect is strongest near phase transitions. We demonstrate a giant electrocaloric effect (0.48 kelvin per volt) in 350-nanometer PbZr(0.95)Ti(0.05)O3 films near the ferroelectric Curie temperature of 222 degrees C. A large electrocaloric effect may find application in electrical refrigeration.
The carrier concentration of the electron-selective layer (ESL) and hole-selective layer can significantly affect the performance of organic-inorganic lead halide perovskite solar cells (PSCs). Herein, a facile yet effective two-step method, i.e., room-temperature colloidal synthesis and low-temperature removal of additive (thiourea), to control the carrier concentration of SnO quantum dot (QD) ESLs to achieve high-performance PSCs is developed. By optimizing the electron density of SnO QD ESLs, a champion stabilized power output of 20.32% for the planar PSCs using triple cation perovskite absorber and 19.73% for those using CH NH PbI absorber is achieved. The superior uniformity of low-temperature processed SnO QD ESLs also enables the fabrication of ≈19% efficiency PSCs with an aperture area of 1.0 cm and 16.97% efficiency flexible device. The results demonstrate the promise of carrier-concentration-controlled SnO QD ESLs for fabricating stable, efficient, reproducible, large-scale, and flexible planar PSCs.
This paper provides a detailed overview of developments in transducer materials technology relating to their current and future applications in micro-scale devices. Recent advances in piezoelectric, magnetostrictive and shape-memory alloy systems are discussed and emerging transducer materials such as magnetic nanoparticles, expandable micro-spheres and conductive polymers are introduced. Materials properties, transducer mechanisms and end applications are described and the potential for integration of the materials with ancillary systems components is viewed as an essential consideration. The review concludes with a short discussion of structural polymers that are extending the range of micro-fabrication techniques available to designers and production engineers beyond the limitations of silicon fabrication technology.
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