In this study, a novel slow-release fertilizer (SRF) consisting of kaolinite and K2SO4 was prepared, employing the process of mechanochemical milling in a planetary ball mill. To obtain the optimum milling time and speed, several samples were made at fixed mass ratios of kaolinite: K2SO4 (3:1). The milling rotational speed ranged from 200 to 700 rpm for 120 min. Different milling times ranging from 60 to 180 min at fixed 600 rpm milling speed were also investigated to evaluate the incorporation of K2SO4 and to measure the liberation of K+ and SO42− ions into solution. The properties of the studied samples were analyzed by Fourier transformation infrared spectrometry (FTIR), thermal gravimetric analysis (TGA), and ion chromatography (IC). The mechanochemical process is a green chemistry procedure that is successfully applied to incorporate K2SO4 into the amorphous kaolinite structure. The slow-release performance was evaluated by determining the K+ and SO42− content in the aqueous solution upon leaching. The optimum released amount of K+ after 24 h was 32 mg L−1 for the milling conditions of 180 min and 700 rpm, indicating that K2SO4-kaolinite has good slow-release properties. The novel SRF is cost-effective, environmentally friendly, and improves the fertilizer’s efficiency in many agricultural applications.
The Sun is a huge and clean energy source that must be relied upon to reduce greenhouse gases and promote the renewable and sustainable energy transition. In this paper, the testing of Al, Cu, and Fe metals with different thicknesses, both bare and painted matte black, was investigated for solar water heating systems. The used technique was a direct contact flat solar heating system (DCFSHS). Many experiments were run to assess this system in terms of metals’ thicknesses and their thermal conductivities as well. Thicknesses of around 0.35 mm and 1 mm of Cu gave almost similar feedback. Maximum temperatures in the range of 93–97 °C were achieved during the autumn season in Amman, Jordan, while it was approximately 80 °C in winter. It has been confirmed that high water temperatures can be obtained in all used metals, regardless of their thermal conductivities. It was also found that a white color of the solar heater case inner wall leads to an increase in water temperature of approximately 4 °C in comparison to a black color. Furthermore, a light reflectance % test in the wavelength range of 240–840 nm for the studied metals, with both bare and black-painted surfaces, gave a superb result that was in line with the obtained results of the DCFSHS. Our innovative system design for solar water heating is due to improvements in many aspects, such as design, production costs, environment, and weight.
A growing number of synthetic plastics derived from fossil fuels are produced, and improper plastic waste management has caused a lot of pollution problems. There are many microplastics in the environment, and they disintegrate slowly in soil and water. The properties of microplastics (MPs) include long residence times, high stability, high fragmentation potential, and the ability to adsorb other contaminants. Invertebrates and planktonic organisms are easily able to accumulate microplastics in aquatic species. Therefore, microplastics (MPs) must be removed from the water and other media. This paper aims to review the occurrence, raw polymers and additives, and remediation methods for removing microplastics from the environment. Several methods are available for removing contaminants, including sorption, filtration and chemical treatments. Various removal methods are discussed along with their methods, efficiency and advantages.
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