We demonstrate highly efficient cavity ringdown spectroscopy in which a broad-bandwidth optical frequency comb is coherently coupled to a high-finesse optical cavity that acts as the sample chamber. 125,000 optical comb components, each coupled into a specific longitudinal cavity mode, undergo ringdown decays when the cavity input is shut off. Sensitive intracavity absorption information is simultaneously available across 100 nanometers in the visible and near-infrared spectral regions. Real-time, quantitative measurements were made of the trace presence, the transition strengths and linewidths, and the population redistributions due to collisions and the temperature changes for molecules such as C2H2, O2, H2O, and NH3.

We demonstrate phase stable, mJ-level parametric amplification of pulse pairs originating from a Ti:Sapphire frequency comb laser. The amplifier-induced phase shift between the pulses has been determined interferometrically with an accuracy of ≈ 10 mrad. Typical phase shifts are on the order of 50-200 mrad, depending on the operating conditions. The measured phase-relation can be as stable as 20 mrad rms (1/300 th of an optical cycle). This makes the system suitable for Ramsey spectroscopy at short wavelengths by employing harmonic upconversion of the double-pulses in nonlinear media.

Optical and radio frequency standards located in JILA and National Institute of Standards and Technology (NIST) laboratories have been connected through a 3.45-km optical fiber link. An optical frequency standard based on an iodine-stabilized Nd:YAG laser at 1064 nm (with an instability of ϳ4 ϫ 10 Ϫ14 at 1 s) has been transferred from JILA to NIST and simultaneously measured in both laboratories. In parallel, a hydrogen maser-based radio frequency standard (with an instability of ϳ2.4 ϫ 10 Ϫ13 at 1 s) is transferred from NIST to JILA. Comparison between these frequency standards is made possible by the use of femtosecond frequency combs in both laboratories. The degradation of the optical and rf standards that are due to the instability in the transmission channel has been measured. Active noise cancellation is demonstrated to improve the transfer stability of the fiber link.