Nitrogen‐15 and Carbon‐13 Chemical Shifts and 13C‐1H, 13C‐15N and 15N‐15N Coupling Constants of Parasubstituted Arene Diazonium Salts
Nitrogen‐15 and carbon‐13 chemical shifts and 13C‐1H,13C‐15N and 15N‐15N coupling constants of 15N‐enriched p‐substituted arene diazonium salts are reported and within the ΔE‐approximation investigated. It is shown that changes of ΔE should be taken into account when considering variation of the nitrogen‐15 chemical shifts. The influence of substituent effects was discussed within the DSP (dual substituent parameter)‐approach.
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