The ability of superhydrophobic surfaces to resist wetting and repel impinging water droplets is not less important for practical applications than the contact angle and contact angle hysteresis. Here we study novel hydrophobic concrete (with the potential for superhydrophobicity) and its ability to repel incoming droplets (e.g., rain). It is found that the onset of the pinning mode can be delayed by changing the surface topography. Also, the pinning or breakup of droplets of higher velocities depends on the incoming angle. Hydrophobic concrete with better pinning resistance showed less tendency for ice accretion.
Abstract:Tribology involves the study of friction, wear, lubrication, and adhesion, including biomimetic superhydrophobic and icephobic surfaces. The three aspects of icephobicity are the low ice adhesion, repulsion of incoming water droplets prior to freezing, and delayed frost formation. Although superhydrophobic surfaces are not always icephobic, the theoretical mechanisms behind icephobicity are similar to the entropically driven hydrophobic interactions. The growth of ice crystals in saturated vapor is partially governed by entropically driven diffusion of water molecules to definite locations similarly to hydrophobic interactions. The ice crystal formation can be compared to protein folding controlled by hydrophobic forces. Surface topography and surface energy can affect both the icephobicity and hydrophobicity. By controlling these properties, micro/nanostructured icephobic concrete was developed. The concrete showed ice adhesion strength one order of magnitude lower than regular concrete and could repel incoming water droplets at´5˝C. The icephobic performance of the concrete can be optimized by controlling the sand and polyvinyl alcohol fiber content.
Lotus (Nelumbo nucifera) is known for its two remarkable properties: superhydrophobicity and thermogenesis; however, the relationship between these two properties remains obscure. Most botanists agree that thermogenesis helps to attract pollinators, while non-wetting helps to catch pollinators and prevents contamination. Here we investigate the surface micro- and nanotopography and wetting properties of eastern skunk cabbage (Symplocarpus foetidus), another thermogenic plant, which is known for its ability to melt snow. The skunk cabbage leaves are hydrophobic but not superhydrophobic, and they have high contact angle hysteresis (similar to the rose petal effect). We develop a heat transfer model to relate icephobicity with heat transfer and discuss the biomimetic potential that both thermogenic and superhydrophobic plants may have for icephobicity in soft materials.
This paper discusses the observations of the Atmospheric Surface Layer (ASL) parameters during the solar eclipse of August 11th, 1999. Intensive surface layer experiments were conducted at Ahmedabad (23 • 21 N, 72 • 36 E), the western part of India, which was close to the totality path. This rare event provided by nature is utilised to document the surface layer effects during the eclipse period using measurements of high frequency fluctuations of temperature, tri-axial wind components as well as mean parameters such as temperature, humidity, wind speed and subsoil temperature. Analysis showed that during the eclipse period, the turbulence parameters were affected leading to the suppression of the turbulence process, the main dynamic process in the atmospheric boundary layer, while the mean parameters showed variations within the natural variability of the observational period. The spectra of the wind components and temperature indicated decrease in spectral power by one order in magnitude during the eclipse period. The rate of dissipation of turbulent kinetic energy is found to decrease by more than one order during the eclipse period. The stability parameter showed a change from unstable to stable condition during the period of eclipse and back to unstable condition by the end of eclipse. lowing the solar eclipse. Eaton et al (1997) provided evidence for the decrease in refractive index structure parameter and diminishing of the turbulence
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