Energy Research and Development Roadmap and industry stakeholders by evaluating optically based instrumentation and control (I&C) concepts for advanced small modular reactor (AdvSMR) applications. These advanced designs will require innovative thinking in terms of engineering approaches, materials integration, and I&C concepts to realize their eventual viability and deployment. The primary goals of this report include:1. Establish preliminary I&C needs, performance requirements, and possible gaps for AdvSMR designs based on best-available published design data.2. Document commercial off-the-shelf (COTS) optical sensors, components, and materials in terms of their technical readiness to support essential AdvSMR in-vessel I&C systems.3. Identify technology gaps by comparing the in-vessel monitoring requirements and environmental constraints to COTS optical sensor and materials performance specifications.4. Outline a future research, development, and demonstration (RD&D) program plan that addresses these gaps and develops optical-based I&C systems that enhance the viability of future AdvSMR designs.The DOE-NE roadmap outlines RD&D activities intended to overcome technical barriers that currently limit advances in nuclear energy. As part of this strategy, DOE-NE is sponsoring research on advanced reactor supportive technologies to reduce the identified barriers. Key challenges that must be overcome include the high capital costs to develop nuclear power plants, maintaining safety performance as the reactor fleet expands, minimizing nuclear waste, and maintaining strong proliferation resistance. AdvSMR designs are a major component of this strategy, because these designs offer a number of unique advantages. The modular and small size of AdvSMR designs naturally lead to reduced capital investments and, potentially, construction savings through factory fabrication. However, new economic and technical challenges accompany the many attractive features offered by AdvSMR designs. Specifically, the modest power output of AdvSMRs does not provide the economy of scale afforded by large reactors. In addition, many of the AdvSMR designs operate at much higher temperatures than lightwater reactors and require instrumentation to withstand harsh, in-vessel environments arising from unconventional, chemically aggressive coolants and unique reactor system configurations.Addressing these I&C challenges will be critically important to the AdvSMR development program to ensure the viability and future success of advanced reactor designs. Solutions will likely be found through evolution of conventional reactor technology, and the development of entirely new concepts. Early pressure/boiling water reactors used conventional I&C technologies (e.g., thermocouples, ionchambers, strain-gauge pressure sensors) to satisfy design requirements. Because these technologies worked well in the relatively low-temperature reactor designs, the demand for alternate I&C technologies was limited. At the time, optical-based reactor monitoring concepts were g...

In this study, the outcome of adding n-butyl alcohol to jatropha methyl ester on the emissions characteristics of compression ignition engines is investigated. Single cylinder diesel engine was fuelled with n-butyl alcohol / jatropha methyl ester blends. The doping volume of n-butyl alcohol to jatropha methyl ester blends was in the range of 10, 20 and 30%. Emission parameters such as Hydro carbon (HC), Carbon monoxide (CO), Nitrogen oxides (NOX) and Smoke emissions were examined at different load conditions. The engine speed was maintained constant throughout the trail. This work resulted in a significant reduction in reduction in all the emissions. Addition of n-butyl alcohol as additive improves the rate of combustion, mixing and vaporization of the blends with air and reduces the emissions associated with it. Further, it can be used in the existing engine with any modification. This also results that the addition of n-butyl alcohol to jatropha methyl ester reduces the emissions associated with it. Further, no damage to engine components was observed during the trail.

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This report presents a hierarchical multiscale modeling scheme based on two-way information exchange. To account for all essential phenomena in waste forms over geological time scales, the models have to span length scales from nanometer to kilometer and time scales from picoseconds to millennia. A single model cannot cover this wide range, and a multi-scale approach that integrates a number of different atscale models is called for. The approach outlined here involves integration of quantum mechanical calculations, classical molecular dynamics simulations, kinetic Monte Carlo and phase field methods at the mesoscale, and continuum models. The ultimate aim is to provide science-based input in the form of constitutive equations to integrated performance and safety codes. The atomistic component of this scheme is demonstrated in the promising waste form xenotime. Density functional theory calculations have yielded valuable information about defect formation energies. This data can be used to develop interatomic potentials for molecular dynamics simulations of radiation damage. Potentials developed in the present work show a good match for the equilibrium lattice constants, elastic constants and thermal expansion of xenotime. In novel waste forms, such as xenotime, a considerable amount of data needed to validate the models is not available. Integration of multiscale modeling with experimental work is essential to generate missing data needed to validate the modeling scheme and the individual models. Density functional theory can also be used to fill knowledge gaps. Key challenges lie in the areas of uncertainty quantification, verification and validation, which must be performed at each level of the multiscale model and across scales. The approach used to exchange information between different levels must also be rigorously validated. The outlook for multiscale modeling of waste forms is quite promising.

We identify the state of the art, gaps in current understanding, and key research needs in the area of modeling the long-term degradation of ceramic waste forms for nuclear waste disposition. The directed purpose of this report is to define a roadmap for Waste IPSC needs to extend capabilities of waste degradation to ceramic waste forms, which overlaps with the needs of the subcontinuum scale of FMM (fundamental methods and method) interests. The key knowledge gaps are in the areas of i) methodology for developing reliable interatomic potentials to model the complex atomic-level interactions in waste forms; ii) characterization of water interactions at ceramic surfaces and interfaces; and iii) extension of atomic-level insights to the long time and distance scales relevant to the problem of actinide and fission product immobilization.