In recent years, environmental concerns have urged companies in the energy sector to modify their industrial activities to facilitate greater environmental stewardship. For example, the practice of unconventional oil and gas extraction has drawn the ire of regulators and various environmental groups due to its reliance on millions of barrels of fresh water—which is generally drawn from natural sources and public water supplies—for hydraulic fracturing well stimulation. Additionally, this process generates two substantial waste streams, which are collectively characterized as flowback and produced water. Whereas flowback water is comprised of various chemical additives that are used during hydraulic fracturing; produced water is a complex mixture of microbiota, inorganic and organic constituents derived from the petroliferous strata. This review will discuss the obstacles of managing and treating flowback and produced waters, concentrating on the hardest constituents to remove by current technologies and their effect on the environment if left untreated. Additionally, this work will address the opportunities associated with repurposing produced water for various applications as an alternative to subsurface injection, which has a number of environmental concerns. This review also uses lithium to evaluate the feasibility of extracting valuable metals from produced water using commercially available technologies.

Environmental concerns with unconventional oil and gas development are frequently centered on elevated water usage and the induction of seismic events during waste disposal. Reuse of produced water for subsequent production well stimulation can effectively address these concerns, but the variability among such samples must be well understood. Twenty-four samples of wastewater from unconventional oil and gas development were collected from south and west Texas to assess their variability and feasibility for direct reuse. Bulk metrics were collected, including total organic carbon, total nitrogen, as well as total dissolved and suspended solids. The profiles of pertinent inorganic constituents were also evaluated. Variations were not only seen between regions but also among samples collected from the same region. For example, the average total organic carbon for Eagle Ford samples collected was 700 ± 500 mg/L, while samples collected from the Permian Basin featured an average total organic carbon concentration of 600 ± 900 mg/L. The Permian Basin total organic carbon ranged from 38 to 2600 mg/L. The total dissolved solids levels had the same variability between regions, with an average value for Eagle Ford of 20,000 ± 10,000 mg/L and a Permian Basin value of 150,000 ± 40,000 mg/L. However, samples were more reproducible within a given region. Collectively, the data indicate that the direct reuse of raw produced water for subsequent production well development without treatment is not feasible based on the reported reuse thresholds. Unconventional development wastewater samples from the Permian Basin were also compared to produced water values from conventional oil and gas wells in the same region, as reported by the United States Geological Survey. Samples collected in the Permian Basin consistently demonstrated lower ionic strength compared to conventional produced water data.

Hydraulic fracturing utilizes pressurized liquid typically consisting of water, proppants, and a multitude of chemical additives, in order to fracture petroliferous strata to extract natural gas and oil. In this process, a vast amount of wastewater is produced. This water is heavily contaminated, which renders it unusable outside of direct reuse, without extensive treatment being performed. Typically, various sophisticated analytical techniques are involved in the characterization of both waste and treated waters, increasing the cost and the complexity of the management efforts. The article discusses the constituents found in oilfield wastewater, the methods used to identify and quantify these constituents, and the present management methods. Additionally, we introduce total organic carbon and conductivity analyses as surrogate measurements of overall water quality. Total organic carbon and conductivity are established bulk measurements, which can be used to facilitate rapid decisions regarding the treatment and greater utilization of flowback and produced oilfield wastes. The application of the proposed surrogates could be used to streamline the current myriad of complex and expensive measurements. This would improve operational efficiency with respect to wastewater management in the energy sector.