A simple, multi component, one-pot method has been reported for the synthesis of poly substituted imidazoles in presence of magnetically separable and recyclable spinel nano copper ferrite as heterogeneous catalyst by the cyclo-condensation of benzil, aromatic aldehyde, ammonium acetate and substituted amines under ultrasonic irradiation. This method of preparation has many advantages compared to those methods which are previously reported in the literature. This methodology offers simple experimental procedure, milder reaction conditions and environmentally benign approach.
Summary
The renewable energy (e.g., solar photovoltaic)‐based grid‐connected microgrid (MG) with composite energy storage system (CESS) is feasible to ensure sustainable and quality power to the commercial and domestic load demands. Effective control systems provide the dynamic performance of such deployed MGs. This paper investigates the application of the finite control‐set model predictive controller (FCS‐MPC) for solar photovoltaic‐based grid‐connected MGs with composite energy storage. FCS‐MPC considers the discrete nature of interfacing (DC–AC and DC–DC) converters into the control algorithm to predict the optimal control command for reference current tracking. Compared to classical control approaches, FCS‐MPC provides a fast‐dynamic response, discards the modulation stage, and effectively handles the effects of dynamic source and load variations and nonlinear loads. The control system encapsulates a proportional–integral (PI) controller, low‐pass filter (LPF), power management algorithm (PMA) unit, and followed by the FCS‐MPC approach. The CESS unit consists of a battery and supercapacitor storage system. The efficacy of the FCS‐MPC approach is verified through the MATLAB/Simulink results. Solar photovoltaic variation due to irradiance, utility grid availability, electricity pricing, and dynamic load variations are considered in the implementation. Furthermore, real‐time simulation of the proposed method is validated using OPAL‐RT OP4510 real‐time simulator.
A microwave irradiated magnetically separable nano cobalt ferrite catalyzed green method for the synthesis of 4-phenyl-4H-pyrano[3,2-h]quinolin-2-amine and 2-amino-4-phenyl-4H-pyrano[3,2-h] quinoline-3-carbonitrile derivatives through cyclization of aromatic aldehyde, acetonitrile/malononitrile and 8-hydoxyquinoline is developed and presented in this paper. The cubic magnetic cobalt ferrite nano particles were synthesized by sol-gel citrate precursor method and characterized by FT-IR, XRD, SEM and TEM techniques and the structures of the synthesized pyranoquinoline derivatives were assigned by IR, MASS and 1 H NMR techniques. The reaction is carried out in a domestic microwave oven with a heat-resistant microwave safe glass container with a lid.
An efficient greener one pot synthesis of dimethyl-dihydro-7H-chromeno[3, 2-h]quinolin-8(9H)-one derivatives has been synthesized through cyclization of aromatic aldehyde, dimidone and 8-hydroxy-quinoline through one-pot condensation method is described. The synthesized compounds are screened for further biological activities against Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus, Bacillus subtilis, Bacillus using cut plate method and disc diffusion method.
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