Electronic and photonic fiber devices that can sustain large elastic deformation are becoming key components in a variety of fields ranging from healthcare to robotics and wearable devices. The fabrication of highly elastic and functional fibers remains however challenging, which is limiting their technological developments. Simple and scalable fiber-processing techniques to continuously codraw different materials within a polymeric structure constitute an ideal platform to realize functional fibers and devices. Despite decades of research however, elastomeric materials with the proper rheological attributes for multimaterial fiber processing cannot be identified. Here, the thermal drawing of hundreds-of-meters long multimaterial optical and electronic fibers and devices that can sustain up to 500% elastic deformation is demonstrated. From a rheological and microstructure analysis, thermoplastic elastomers that can be thermally drawn at high viscosities (above 10 Pa s), allowing the encapsulation of a variety of microstructured, soft, and rigid materials are identified. Using this scalable approach, fiber devices combining high performance, extreme elasticity, and unprecedented functionalities, allowing novel applications in smart textiles, robotics, or medical implants, are demonstrated.
Working conditions for fire fighters can be described according to the environment temperature and the incident radiant heat flux. Measurements for this study in buildings for fire fighting training have shown that fire fighters are typically exposed to radiant heat fluxes of between 5 and 10 kWm(-2) during this kind of exercise. The heat load can nevertheless be much higher. In one case, 42 kWm(-2) was measured. The temperatures reached between 100 and 190 degrees C at 1 m above ground, going up to 278 degrees C in one case. Human trials have been performed with 17 fire fighters. After exercises (about 15 min) in a heated room, the mean core temperature of the fire fighters rose by 0.6 degrees C with a surrounding temperature of 31 degrees C and 1.0 degrees C with 38 degrees C. The sweat production varied from 0.7 to 2.1 lh(-1); 16% to 45% of sweat remained in the clothing layers. During the exercises in the training buildings, a mean of 48 degrees C has been measured between fire fighters' clothing and workwear. These conditions lead to an increase of the relative humidity in all the jackets up to 100%. When the fire fighters came out of the fire, the humidity remained at this level in the PVC coated jackets while it was in some cases strongly reduced in breathable jackets.
Current academic and industrial research sustains large efforts to synthesize and develop environmentally responsive smart materials. The temperature‐responsive materials with a trigger temperature in the physiological range attract much attention due to their potential biomedical applications. We describe their chemistry and the way to synthesize them, focusing on applications for smart clothing fabrication. Copyright © 2007 Society of Chemical Industry
For the long-time monitoring of electrocardiograms, electrodes must be skin-friendly and non-irritating, but in addition they must deliver leads without artifacts even if the skin is dry and the body is moving. Today's adhesive conducting gel electrodes are not suitable for such applications. We have developed an embroidered textile electrode from polyethylene terephthalate yarn which is plasma-coated with silver for electrical conductivity and with an ultra-thin titanium layer on top for passivation. Two of these electrodes are embedded into a breast belt. They are moisturized with a very low amount of water vapor from an integrated reservoir. The combination of silver, titanium and water vapor results in an excellent electrode chemistry. With this belt the long-time monitoring of electrocardiography (ECG) is possible at rest as well as when the patient is moving.
Havenith G, Bröde P, den Hartog E, Kuklane K, Holmer I, Rossi RM, Richards M, Farnworth B, Wang X. Evaporative cooling: effective latent heat of evaporation in relation to evaporation distance from the skin. J Appl Physiol 114: 778 -785, 2013. First published January 17, 2013 doi:10.1152/japplphysiol.01271.2012.-Calculation of evaporative heat loss is essential to heat balance calculations. Despite recognition that the value for latent heat of evaporation, used in these calculations, may not always reflect the real cooling benefit to the body, only limited quantitative data on this is available, which has found little use in recent literature. In this experiment a thermal manikin, (MTNW, Seattle, WA) was used to determine the effective cooling power of moisture evaporation. The manikin measures both heat loss and mass loss independently, allowing a direct calculation of an effective latent heat of evaporation (eff). The location of the evaporation was varied: from the skin or from the underwear or from the outerwear. Outerwear of different permeabilities was used, and different numbers of layers were used. Tests took place in 20°C, 0.5 m/s at different humidities and were performed both dry and with a wet layer, allowing the breakdown of heat loss in dry and evaporative components. For evaporation from the skin, eff is close to the theoretical value (2,430 J/g) but starts to drop when more clothing is worn, e.g., by 11% for underwear and permeable coverall. When evaporation is from the underwear, eff reduction is 28% wearing a permeable outer. When evaporation is from the outermost layer only, the reduction exceeds 62% (no base layer), increasing toward 80% with more layers between skin and wet outerwear. In semi-and impermeable outerwear, the added effect of condensation in the clothing opposes this effect. A general formula for the calculation of eff was developed.
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