The electrocatalytic oxidation of hydrogen peroxide has been studied by iodide at the surface of carbon paste electrode. Cyclic voltammetry and chronoamperometry techniques were used to investigate the suitability of iodide as a mediator for the electrocatalytic oxidation of hydrogen peroxide in aqueous solution with various pH. Results showed that pH 8.00 is the most suitable for this purpose. The kinetic process of the catalytic reaction can be explained using cyclic voltammetry and chronoamperometry. The calculated mean value of catalytic rate constant (kh) is determined to be 6.46 × 102 M−1s−1 using chronoamperometry data. In order to obtain the diffusion coefficient of iodide, chronoamperometry method has been used, that the value of D has been calculated 7.16 × 10−1 cm2 s−1. The catalytic oxidation peak current was linearly dependent on the hydrogen peroxide concentration and the linearity range obtained was 1.00 × 10−5 to 1.00 × 10−3 M. Detection limit has been found to be 5.61 × 10−6 M (3σ;). This method can provide a simple and low cost electrochemical sensor for catalytic oxidation detection of hydrogen peroxide in real sample.