No abstract

In this study the effects of a closed-loop recycling methodology are evaluated for degradation using a discontinuous carbon fibre polypropylene (CFPP) composite material. The process comprises two fundamental steps, reclamation and remanufacture. The material properties are analysed over two recycling loops. For neat polypropylene, the molecular weight analysis indicates evidence of minimal matrix degradation that does not affect the material behaviour, as demonstrated by the shear tests. CFPP specimens show no decrease in mechanical properties over repeated loops, the final specimens show an increase of 26 % and 43 % in ultimate tensile strength and ultimate strain, respectively. These are attributed to cumulative matrix residue on the fibre surface after reclamation and subsequently increased fibre-matrix adhesion. The improvement of CFPP properties and insignificant variability in the tensile properties and molecular weight distribution of neat polypropylene validate the potential of this proof-of-concept, closed-loop recyclable material. Future studies will investigate alternative, higher performance matrices.

The effects of a closed-loop recycling methodology are evaluated for degradation using a discontinuous carbon fibre polyamide 6 (CFPA6) composite material. The process comprises two fundamental steps: reclamation and remanufacture. The material properties are analysed over two recycling loops, and CFPA6 specimens show a total decrease of 39.7 % (± 3.5) in tensile stiffness and 40.4 % (± 6.1) in tensile strength. The results of polymer characterisation and fibre analysis suggested that the stiffness reduction was likely due to fibre misalignments primarily caused by fibre agglomerations, as a result of incomplete fibre separation, and by fibre breakages from high compaction pressures. The ultimate tensile strain was statistically invariable as a function of recycling loop which indicated minimal variation in polymer structure as a function of recycling loop. To the authors' best knowledge, the mechanical performance of the virgin CFPA6 is the highest observed for any aligned discontinuous carbon fibre thermoplastic composites in the literature. This is also true for recycled specimens, which are the highest observed for any recycled thermoplastic composite, and, for any recycled discontinuous carbon fibre composite with either thermosetting or thermoplastic matrices.