ChemInform Abstract On heating the four-coordinate 16-electron η2-ethylene-Ir(I) complex (I) completely converts into the six-coordinate hydridovinyl-Ir(III) isomer (II). The half-life of the reaction is 4,5 h at 100 rc C. The new ligand tris(3-(trifluoromethyl)-5-methylpyrazol-1-yl)borate which changes from a bidentate to a three-dentate coordination causes the reversed stability.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.