Nanotechnology is the study and development of materials at nano levels. It is one of the rapidly growing scientific disciplines due to its enormous potential in creating novel materials that have advanced applications. This technology has tremendously impacted many different science and engineering disciplines, such as electronics, materials science, and polymer engineering. Nanofibers, due to their high surface area and porosity, find applications as filter medium, adsorption layers in protective clothing, etc. Electrospinning has been found to be a viable technique to produce nanofibers. An in-depth review of research activities on the development of nanofibers, fundamental understanding of the electrospinning process, and properties of nanostructured fibrous materials and their applications is provided in this article. A detailed account on the type of fibers that have been electrospun and their characteristics is also elaborated. It is hoped that the overview article will serve as a good reference tool for nanoscience researchers in fibers, textiles, and polymer fields. Furthermore, this article will help with the planning of future research activities and better understanding of nanofiber characteristics and their applications.
Perchlorate, an iodide uptake inhibitor, is increasingly being detected in new places and new matrices. Perchlorate contamination has been attributed largelyto the manufacture and use of ammonium perchlorate (the oxidizer in solid fuel rockets) and/or the earlier use of Chilean nitrate as fertilizer (approximately 0.1% perchlorate). However, there are regions such as the southern high plains (Texas Panhandle) where there is no clear historical or current evidence of the extensive presence of rocket fuel or Chilean fertilizer sources. The occurrence of easily measurable concentrations of perchlorate in such places is difficult to understand. In the southern high plains groundwater, perchlorate is better correlated with iodate, known to be of atmospheric origin, compared to any other species. We show that perchlorate is readily formed by a variety of simulated atmospheric processes. For example, it is formed from chloride aerosol by electrical discharge and by exposing aqueous chloride to high concentrations of ozone. We report that perchlorate is present in many rain and snow samples. This strongly suggests that some perchlorate is formed in the atmosphere and a natural perchlorate background of atmospheric origin should exist.
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