Polyvinyl chloride (PVC) is a widely used polymer, not only in industry, but also in our daily life. PVC is a material that can be applied in many different fields, such as building and construction, health care, and electronics. In recent decades, the success of electrospinning technology to fabricate nanofibers has expanded the applicability of polymers. PVC nanofibers have been successfully manufactured by electrospinning. By changing the initial electrospinning parameters, it is possible to obtain PVC nanofibers with diameters ranging from a few hundreds of nanometers to several micrometers. PVC nanofibers have many advantages, such as high porosity, high mechanical strength, large surface area, waterproof, and no toxicity. PVC nanofibers have been found to be very useful in many fields with a wide variety of applications such as air filtration systems, water treatment, oil spill treatment, batteries technology, protective clothing, corrosion resistance, and many others. This paper reviews the fabricating method, properties, applications, and prospects of PVC nanofibers.

Chitosan/PVA nanofibrous electroresponsive soft actuators were successfully obtained using an electrospinning process, which showed fast speed displacement under an acidic environment. Chitosan/PVA nanofibers were prepared and characterized, and their electroactive response was tested. Chitosan/PVA nanofibers were electrospun from a chitosan/PVA solution at different chitosan contents (2.5, 3, 3.5, and 4 wt.%). Nanofibers samples were characterized using Fourier transform infrared analyses, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), optical microscopy, and tensile test. The electroactive behavior of the nanofiber hydrogels was tested under different HCl pH (2–6) under a constant voltage (10 V). The electroactive response test showed a dependence between the nanofiber’s chitosan content and pH with the bending speed displacement, reaching a maximum speed displacement of 1.86 mm−1 in a pH 3 sample with a chitosan content of 4 wt.%. The results of the electroactive response were further supported by the determination of the proportion of free amine groups, though deconvoluting the FTIR spectra in the range of 3000–3700 cm−1. Deconvolution results showed that the proportion of free amine increased as the chitosan content was higher, being 3.6% and 4.59% for nanofibers with chitosan content of 2.5 and 4 wt.%, respectively.