If siloxycarbene formation involves initial -cleavage this would be the -cleavage rate constant.(15) We have no definitive evidence at present on the multiplicity (singlet or triplet) of the siloxycarbene state which reacts with alcohol.(16) See: (Dalton, J. €.; Bourque, R. A. J. Am. Chem. Soc. 1981, following paper in this issue) for an interesting example of an acylsilane photoreaction that does not involve siloxycarbene intermediates.Mechanistic Photochemistry of Acylsilanes. 2.

No abstract

No abstract

Acylsilane bilden bei Bestrahlung in Alkoholen Acetale.

No abstract