591liydrutropic salts such as sodiuin benzoate or sodium xylene sulfonate, sodium iodide was relatively ineffective as a solulilizing agent, giving only a 10% increase in acrylonitrile solubility even in the absence of alkalies. These workers observed that at higher alkali concentrations, the acrylonitrile was &dquo;salted out&dquo; hy the sodium iodide-sodium hydroxide mixture more readily than if no sodium iodide were present. > Their solubility measurements were made at 25°C, while the cyanoethylation was conducted at 60°C. It is, of course, possible that at the higher temperature, sodium iodide would show appreciable hy-drotrol>ic action for acrylonitrile in the 2.3% sodium hydroxide used for cyanoethylation. Evidence on this question is still lacking.'Vhether alkali iodides exert appreciable soluhilizing effects on benzyl chloride is unknown. At the high concentrations of alkali ( 18-23% ) used in benzylation, the existing evidence suggests hydrotropic effects would not contribute significantly to the observed catalysis, though they might offset salting-out effects which would otherwise prevent the catalysis from occurring. _ ' ' Acknowledgment The authors wish to express their appreciation to members of Textile Testing Investigations for the breaking strength determinations included in this report.
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