We investigate, for an arbitrary initial condition, the time dependent solutions for a fractional Schrödinger equation in the presence of delta potentials by using the Green function approach. The solutions obtained show an anomalous spreading asymptotically characterized by a power-law behavior, which is governed by the order of the fractional spatial operator present in the Schrödinger equation.

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The Poisson-Nernst-Planck (PNP) diffusional model for the immittance or impedance spectroscopy response of an electrolytic cell in a finite-length situation is extended to a general framework. In this new formalism, the bulk behavior of the mobile charges is governed by a fractional diffusion equation in the presence of a reaction term. The solutions have to satisfy a general boundary condition embodying, in a single expression, most of the surface effects commonly encountered in experimental situations. Among these effects, we specifically consider the charge transfer process from an electrolytic cell to the external circuit and the adsorption-desorption phenomenon at the interfaces. The equations are exactly solved in the small AC signal approximation and are used to obtain an exact expression for the electrical impedance as a funcion of the frequency. The predictions of the model are compared to and found to be in good agreement with the experimental data obtained for an electrolytic solution of CdCl2H2O.

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Surface effects on a diffusion process governed by a fractional diffusion equation in a confined region with spatial and time dependent boundary conditions are investigated. First, we consider the one-dimensional case with the boundary conditions rho(0,t)=Phi0(t) and rho(a,t)=Phia(t). Subsequently, the two-dimensional case in the cylindrical symmetry with rho(a,theta,t)=Phia(theta,t) and rho(b,theta,t)=Phib(theta,t) is investigated. For these cases, we also obtain exact solutions for an arbitrary initial condition by using the Green's function approach.