Two tetranortriterpenoids, kokosanolide A (1) and C (2) were isolated from the seeds and three onoceranoid-type triterpenoids: kokosanolide B (3), 8,14-secogammacera-7,14-diene-3,21-dione (4) and a 1.5:0.5 mixture of 8,14-secogammacera-7,14(27)-diene-3,21-dione (5) and compound 4 were isolated from the bark of kokossan (Lansium domesticum). Complete 1H- and 13C-NMR data of the triterpenoids 1-5 are reported. The triterpenoids’ structures were elucidated primarily by means of high field 1D- and 2D-NMR, IR and HRMS spectral data. Triterpenoids 1-5 exhibited moderate to strong antifeedant activity against the fourth instar larvae of Epilachna vigintioctopunctata.
As a semiconductor, zinc oxide (ZnO) has better UV absorbing properties compared to other semiconductor materials, and therefore, it has better dye degrading abilities. However, ZnO tends to agglomerate, which lead to poor degradation compared to the other semiconductors. In this study, to overcome the agglomeration of ZnO, silica (SiO 2) was combined with ZnO. The composite was tested for its photocatalytic activity. The ZnO/SiO 2 photocatalyst was fabricated on a glass plate. In order to investigate the addition of SiO 2 on ZnO, X-ray diffraction (XRD) and scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS) was used. The result of the XRD analysis demonstrates similar peak results with ZnO XRD data from ICSD 157132 with a hexagonal structure. The results indicate that the ZnO structure did not change after the addition of SiO 2 , while SEM-EDS results showed that SiO 2 was supported on ZnO with 8% composition. The optimal composition was found to be ZnO/SiO 2 95/5, as indicated by high degradation activity, which can degrade up to 89% methylene blue.
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