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Fe−Pd nanoparticles are immobilized in stimuliresponsive poly-N-isopropylacrylamide (PNIPAm)-and polymethyl methacrylate-functionalized polyvinylidene fluoride membranes using ion exchange for 2-chlorobiphenyl (PCB-1) degradation via the reductive pathway. PNIPAm is introduced into the reactive membrane system, and its thermoresponsive behavior is leveraged to enhance PCB-1 diffusion and adsorption into the reactive domain. The surface area-normalized rate constant (k SA ) values were determined in the convective flow mode to be 0.13, 0.28, 0.72, and 1.36 L/m 2 /g at 15, 25, 35, and 45 °C, respectively, with an activation energy of 60 kJ/mol (3 wt % Pd). The diffusion coefficients for PCB-1 were 6.6 × 10 −11 and 8.7 × 10 −11 m 2 /s at 25 and 35 °C, respectively. The adsorption of PCB-1 onto PNIPAm hydrogels also increased from 40 to 70% as the temperature was increased above its lower critical solution temperature of 32 °C. The batch-mode k SA values were 0.12 L/m 2 /h at 25 °C and 0.35 L/m 2 /h at 35 °C.

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