The ethylene oxide hydration process in a catalytic fixed bed tube reactor was studied. A cross-linked styrene-divinylbenzene anion-exchange resin in the HCO 3 -/CO 3 2--form was used as a catalyst. The deactivation and swelling of the catalyst during the process were detected. The mathematical model of the reactor with determined parameters adequately describing the rate of the reaction, product distribution and catalyst deactivation and swelling has been developed.
Butyl lactate is a green solvent produced from renewable materials through the reaction of ammonium lactate with n-butanol. It could be a source material for valuable products such as propylene glycol, acrylic acid, its derivatives, and the cyclic monomer of polylactic acid (PLA)—lactate. In this study, we present novel non-catalytic interactions of ammonium lactate and n-butanol carried out in the temperature range of 130–170 °C in a closed system. The study focused on the kinetic modelling of the reaction between ammonium lactate and n-butanol to derive a mathematical model for the reactor unit of butyl lactate synthesis. The aim of this work was to study the kinetics of the interaction between ammonium lactate and n-butanol, as well as to obtain a kinetic model of the process and its parameters. We suggested the chemical transformation routes and determined the kinetic model and parameters that adequately describe the process in a closed system within the studied condition range. The study proposes the first kinetic model that accounts for lactamide formation through two routes. This study showed that the high-temperature non-catalytic interaction of ammonium lactate and n-butanol could be one of the prospective synthesis routes.
This research focuses to studying on the process of glycolysis of polycarbonate (PC) catalyzed by zinc chloride. The degradation of polyester into monomers (bisphenol A, or BPA, and ethylene carbonate, or EC), which may then interact with one another to generate the matching ethers, was discovered to be the process. As a result, the optimal conditions for the depolymerization of PC to obtain bisphenol A and ethylene carbonate with the highest yield were therefore identified as 180 °C, a molar ratio of 11 between EG and PC, and a mass concentration of 0.12% ZnCl2. A scheme of PC glycolysis has been proposed, and a mathematical model adequately describing the experimental data has been developed.
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