The authors report on a solution-processed composite film based on poly(vinylidene fluoride/trifluoroethylene) copolymer and barium titanate (BT) nanopowder, to be used as ferroelectric high-κ gate insulation in organic field-effect transistors (OFETs). Flexible films of up to 50vol% BT powder content are produced by preparing homogeneous dispersion of the powder in the polymer solutions. The films exhibited high specific volume resistivities combined with dielectric constants of up to 51.5 at 1kHz. Low-voltage OFETs with ferroelectric hysteresis and good memory retention properties were demonstrated by using the composite films.
This paper presents a detailed study on the properties of different polymer inks based on poly(3,4eth-ylenedioxythiophene)/polystyrenesulfonate regarding their processability in an experimental piezo driven drop-ondemand (DoD) micro-feeding system. Based on the rheological properties of the used inks and the mechanical properties of the printing system characteristic values are derived which allow to predict the processability of polymer inks in a given printing system. Beside the printability the influence of different polymer inks on the electrical characteristics of printed organic field effect transistors is investigated.
The authors present a strategy to manufacture wavelength-selective field-effect phototransistors by employing dye-doped poly-3-hexylthiophene (P3HT) as a semiconducting layer. The dye doping of the semiconductor P3HT was achieved by blending organic molecules—coumarin 6, oxazine 1, and nile red—into the conjugated organic polymer. Illuminating these transistors with monochromatic light in the range of 400–700nm resulted in varying conductivities for certain wavelengths in dependence on the particular dye. This effect is attributed to the photogeneration of excitons on the dye molecules, which are subsequently transferred to the conjugated polymer.
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