Activated carbons (ACs) prepared from apple pulp and apple peel with phosphoric acid as an activation agent under microwave radiation were investigated. The effects of microwave radiation power and time on the adsorption capacities of the ACs were studied. The optimum AC preparation condition was identified by comparing the MB adsorption capacities of the produced ACs. The obtained results show that the microwave radiation power and time had strong effects on the adsorption capacities. Relative to conventional heating methods, microwaveprepared ACs showed higher BET surface areas and mesopore volumes after a shorter activation time due to differences in the type of heat transfer between these two methods. The N 2 adsorption isotherms at −196°C and SEM and FTIR results were used to characterize the properties of the prepared ACs. The N 2 adsorption results revealed BET surface areas of 1552 m 2 /g and 1103 m 2 /g for apple-peel and apple-pulpbased AC, respectively.
This is a repository copy of An investigation on the capability of magnetically separable Fe O /mordenite zeolite for refinery oily wastewater purification ₃ ₄ .
This paper presents a case study on the crude oil atmospheric distillation column of Tabriz refinery plant to show the applicability of exergy loss profiles in thermodynamic examination of the different retrofit options. The atmospheric distillation column of Tabriz refinery has been revamped as a consequence of increase of the plant capacity to 100,000 bpd. To cover the deficit of feedstock of the revamped unit, a blend of the existing feedstock with imported crude oil is used as a feedstock. However, to investigate how the blend of these two different types of crudes as a feedstock has an influence on the operating conditions, the examination of the column is needed. Exergy as a comprehensive thermodynamic property which translates the temperature, pressure and composition change into a common unit has been chosen to evaluate the distillation column thermodynamically. Furthermore, the exergy loss profile of the base case serves as a scoping tool to pinpoint the source of inefficiencies. Then, the exergy loss profile as a screening tool has found the retrofit options which are likely to yield greatest energy saving from a list of retrofit options proposed by the industrial partner. In the presented case study, the exergy loss profile identifies the best retrofit option with 17.16% reduction in exergy losses, which finally lead to 3.6% reduction of primary fuel demand.
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