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Colloidal assembly of nC60 fullerene with naturally abundant magnetic iron oxide NPs will affect their fate and transformation in environmental media. In solution, fullerene association to aggregating iron oxide NPs/clusters greatly enhanced the overall colloidal stability. Development of depletion-mediated structured fullerene layers between pure and surface modified γFe2O3 NPs possibly resulted in such stabilization. Here, we also report that on air-water interface, association of fullerene to pure and humic acid (HA7) coated γFe2O3 NPs led to the formation of ordered assemblies, e.g., binary wires and closed-packed "crystalline" and "glassy" structures in the presence and absence of electrolytes suggesting immobilization of the former. The interaction of fullerene to Fe3O4 NPs and clusters also produced ordered assemblies along with amorphous aggregates. Fullerene interaction with Fe3O4 NPs in low concentration of HA1 and Na(+) at pH 6 formed dendritic growth and polycrystalline circular assemblies on air-water interface. HRTEM study further revealed that the monolayer circular assemblies were highly ordered but structural degeneracy was evident in multilayers. Therefore, interfacial assemblies of fullerene with iron oxide NPs resulted in short-range periodic structures with concomitant immobilization and reduction in availability of the former, especially in soils or sediments rich in the latter.

High-energy-density storage devices play a major role in modern electronics from traditional lithium-ion batteries to supercapacitors for a variety of applications from rechargeable devices to advanced military equipment. Despite the mass adoption of polymer capacitors, their application is limited by their low energy densities and low-temperature tolerance. Polymer nanocomposites based on 2D nanomaterials have superior capacitive energy densities, higher thermal stabilities, and higher mechanical strength as compared to the pristine polymers and nanocomposites based on 0D or 1D nanomaterials, thus making them ideal for high-energy-density dielectric energy storage applications. Here, the recent advances in 2D-nanomaterial-based nanocomposites and their implications for energy storage applications are reviewed. Nanocomposites based on conducting 2D nanofillers such as graphene, reduced graphene oxide, MXenes, semiconducting 2D nanofillers including transition metal dichalcogenides such as MoS 2 , dielectric 2D nanofillers including hBN, Mica, Al 2 O 3 , TiO 2 , Ca 2 Nb 3 O 10 and MMT, and their effects on permittivity, dielectric strength, capacitive energy density, efficiency, thermal stability, and the mechanical strength, are discussed. Also, the theory and machine-learning-guided design of polymer 2D nanomaterial composites is learnt and the challenges and opportunities for developing ultrahigh-capacitive-energy-density devices based on these nanofiller polymer composites are presented.

Here, we investigated the influence of grain formation on the magnetization reversal of SmCo5/Co at low temperature. A set of SmCo5/Co bi-layer samples were fabricated under identical conditions on MgO(100) and glass substrates with a Cr underlayer. Analysis of each magnetic layer by an Atomic Force Microscope (AFM) reveals that MgO(100) results small and uniform grain formation of 23 nm in contrast to 57 nm on glass, and x-ray diffraction studies show that the sample on MgO(100) has high crystallinity with SmCo5(11 2 0) phase. At room temperature, both samples exhibit good hard magnetic properties with coercivity (HC) of 13.2 kOe and 12.5 kOe, and energy products (BH)max of 14.5 MGOe and 5.3 MGOe for samples on MgO(100) and glass, respectively. Low temperature hysteresis measurements show an exchange decoupling at low temperatures for the sample on glass, and this is due to the formation of large grains on glass that reduces the effective inter-grain exchange coupling between phases.

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