Magnetic anisotropies have key role to taylor magnetic behavior in ferromagnetic systems. Further, they are also essential elements to manipulate the thermoelectric response in Anomalous Nernst (ANE) and Longitudinal Spin Seebeck systems (LSSE). We propose here a theoretical approach and explore the role of magnetic anisotropies on the magnetization and thermoelectric response of noninteracting multidomain ferromagnetic systems. The magnetic behavior and the thermoelectric curves are calculated from a modified Stoner Wohlfarth model for an isotropic system, a uniaxial magnetic one, as well as for a system having a mixture of uniaxial and cubic magnetocrystalline magnetic anisotropies. It is verified remarkable modifications of the magnetic behavior with the anisotropy and it is shown that the thermoelectric response is strongly affected by these changes.Further, the fingerprints of the energy contributions to the thermoelectric response are disclosed.To test the robustness of our theoretical approach, we engineer films having the specific magnetic properties and compare directly experimental data with theoretical results. Thus, experimental evidence is provided to confirm the validity of our theoretical approach. The results go beyond the traditional reports focusing on magnetically saturated films and show how the thermoelectric effect behaves during the whole magnetization curve. Our findings reveal a promising way to explore the ANE and LSSE effects as a powerful tool to study magnetic anisotropies, as well as to employ systems with magnetic anisotropy as sensing or elements in technological applications.

ZnO and doped ZnO films with non-ferromagnetic metal have been widely used as biosensor elements. In these studies, the electrochemical measurements are explored, though the electrical impedance of the system. In this sense, the ferromagnetic properties of the material can be used for multifunctionalization of the sensor element using external magnetic fields during the measurements. Within this context, we investigate the room-temperature ferromagnetism in pure ZnO and Ag-doped ZnO films presenting zigzag-like columnar geometry. Specifically, we focus on the films’ structural and quasi-static magnetic properties and disclose that they evolve with the doping of low-Ag concentrations and the columnar geometry employed during the deposition. The magnetic characterization reveals ferromagnetic behavior at room temperature for all studied samples, including the pure ZnO one. By considering computational simulations, we address the origin of ferromagnetism in ZnO and Ag-doped ZnO and interpret our results in terms of the Zn vacancy dynamics, its substitution by an Ag atom in the site, and the influence of the columnar geometry on the magnetic properties of the films. Our findings bring to light an exciting way to induce/explore the room-temperature ferromagnetism of a non-ferromagnetic metal-doped semiconductor as a promising candidate for biosensor applications.

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