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Enones. -The readily accessible and stable sulfone (II) reacts with pyrazoles, imidazoles, triazoles, and their benzo analogues stereoselectively to form exclusively (E)-isomers of β-azolyl-substituted enones. Quaternization of the azolyl group with methyl triflate (IV) gives rise to salts (V) and (VIII) in quantitative yields. The substantial decrease of the LUMO energy leads to reagents possessing high electrophilicity. -(KRASOVSKY, A. L.; PISSAREV, S. A.; NENAJDENKO*, V. G.; BALENKOVA, E. S.; Russ. Chem. Bull. 52 (2003) 8, 1791-1796; Dep. Chem., Lomonosov Moscow State Univ., Moscow 119992, Russia; Eng.) -H. Hoennerscheid 08-111