No abstract

In the La Sierrita area of Nuevo Leon, Mexico, three spherule layers are present and separated from the overlying siliciclastic deposits by up to 6 m of pelagic marls. The marls are of latest Maastrichtian age (Plummerita hantkeninoides (CF1) Zone, Micula prinsii Zone) and deposited under normal pelagic conditions with no significant evidence of reworking or slumping. Original deposition of the spherule layers occurred during the last 300 ka of the Maastrichtian and well prior to the Cretaceous-Tertiary (K–T) boundary event. Thus, if the spherules in northeastern Mexico provide critical evidence of an impact at Chicxulub, this impact predates the K–T boundary.

Abstract. Stable isotope data from lipid biomarkers and diatom silica recovered from lake sediment cores hold great promise for paleoclimate and paleohydrological reconstructions. However, these records rely on accurate calibration with modern precipitation and hydrologic processes and only limited data exist on the controls on the δD values for n-alkanoic acids from plant leaf waxes. Here we investigate the stable isotopic composition of modern precipitation, streams, lake water and ice cover, and use these data to constrain isotope systematics of the Lake El'gygytgyn Basin hydrology. Compound-specific hydrogen isotope ratios determined from n-alkanoic acids from modern vegetation are compared with modern precipitation and lake core top sediments. Multi-species net (apparent) fractionation values between source water (precipitation) and modern vegetation (e.g., ϵwax/precip mean value is −107 ± 12‰) agree with previous results and suggest a consistent offset between source waters and the δD values of alkanoic acids. We conclude that although there may be some bias towards a winter precipitation signal, overall δD values from leaf wax n-alkanoic acids record annual average precipitation within the El'gygytgyn Basin. A net fractionation calculated for 200-yr-integrated lake sediments yields ϵ30/precip = −96 ± 8‰ and can provide robust net "apparent" fractionation to be used in future paleohydrological reconstructions.

The Cretaceous-Tertiary (K-T) transition in eastern Bulgaria (Bjala) was analyzed in terms of lithology, mineralogy, stable isotopes, trace elements, and planktic foraminifera. The sequence represents a boreal-Tethyan transitional setting, spans from the last 300 k.y. of the Maastrichtian (zone CF1) through the early Danian (zones P0-Plc), and contains several short hiatuses. It differs from low-latitude Tethyan sequences primarily by lower diversity assemblages, pre-K-T faunal changes, a reduced K-T d 13 C shift, and the presence of two clay layers with platinum group element anomalies. The first clay layer marks the K-T boundary impact event, as indicated by an iridium anomaly (6.1 ppb), the mass extinction of tropical and subtropical planktic foraminifera, and cooling. The second clay layer is stratigraphically within the upper Parvularugoglobigerina eugubina (Pla) zone and contains a small Ir enrichment (0.22 ppb), a major Pd enrichment (1.34 ppb), and anomalies in Ru (0.30 ppb) and Rh (0.13 ppb) that suggest a volcanic source.

During the early Palaeocene (zones P1 to P2), the southeastern Tethyan margin experienced a warm and humid climate with high rainfall as indicated by the abundance of kaolinite within marine sedimentary rocks. Subsequently, in Zone P2, arid climatic conditions evolved in the coastal basins of the southern Tethys margin as indicated by the gradual disappearance of kaolinite and the increased abundance of palygorskite and sepiolite. Arid climatic conditions persisted during the Selandian and Thanetian (late Palaeocene) and reached a maximum in the Ypresian (early Eocene). During the late Palaeocene thermal maximum, warm climatic conditions were associated with increased aridity and led to sea surface warming, though not bottom water warming, as suggested by the planktic 18 O excursion observed at the Zomet Telalim basin (Negev, Israel). Strongly reduced surface productivity accompanied by unusually light 13 C are associated with the late Palaeocene thermal maximum in the Negev as well as globally.