Trapped electrons were generated by photoionization of TMPD (N,N,N′,N′-tetramethylparaphenylenediamine) and the absorption spectra measured in 2-methylpentane (2MP), 3-methylpentane (3MP), cis-decalin (CD), methylcyclohexane (MCH), and deuterated methylcyclohexane(dMCH) glasses at 77 K. The low energy absorption fits the Wigner 3/2 power law for threshold photodetachment, consistent with a ground S state with binding energy of 0.48 ( 0.02 eV and a final continuum P state. For all solvents studied, the maximum absorption cross-section is located at ca. 0.7 eV with an extinction coefficient of 2.7 × 10 4 M -1 cm -1 (determined by comparison to TMPD cation). From the spectral distribution of the absorption (from 0.5 to 3.3 eV), experimental oscillator strengths were determined to be 0.65(2MP), 0.63(3MP), and 0.76(CD). Various local field corrections to these experimental oscillator strengths are discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.