This paper demonstrates the application of ultrashort-pulsed lasers as a unique tool for controllable modification of the surface wettability of polymers from high hydrophilicity to superhydrophobicity. This is achieved by exploiting the effect of laser pulse duration and photon energy on the surface chemistry and morphology and subsequent wetting properties of polymeric surfaces treated with UV laser pulses. In three different pulse duration regimes, ranging from femtosecond to nanosecond and two different photon wavelengths, we have systematically altered the wettability of polyethersulfone surfaces from highly hydrophilic to superhydrophobic. Our results indicate that, despite the remarkable changes in the surface morphology attained, the surface wettability variations are dominantly caused by laser-induced chemical modifications, which are highly dependent on the pulse energy and duration. The ability of tuning the wetting properties and thus the surface energy of laser-treated polymer surfaces within a broad range makes them excellent candidates for liquid flow control in microfluidics and biological adhesion applications.

The effect of XeCl laser irradiation on biocompatibility of polyethersulfone (PES) film surface was investigated. For this purpose, the surface of PES film was irradiated with different number of pulses at dif ferent fluences. The treated surfaces were characterized by attenuated total reflectance Fourier transform infrared spectroscopy (ATR FTIR), scanning electron microscopy (SEM), atomic force microscopy (AFM) and contact angle measurements. The platelet adhesion and cell culture measurements were done on the treated surface for investigation of the biocompatibility. It was shown that, irradiation of surface with 500 pulses at a fluence of 25 mJ/cm 2 is the most optimal condition for improving the platelet adhesion on the PES surface with a XeCl laser.

No abstract

No abstract

No abstract