The process of sorption-electrochemical cleaning of rinse waters, obtained after ammonia etching of printed circuit boards from copper ions, is proposed. Cation exchanger KU-2×8 and ampholyte Lewatit MonoPlus TP 207 for the extraction of copper were tested. Capacity up to breakthrough of Lewatit MonoPlus TP 207 is 0.11 g/g and a full dynamic exchange capacity for copper of 0.15 g/g. Various options of a pregnant ion exchanger desorption are considered. The best stripping ability has a 20% solution of sulfuric acid. The possibility of desorption by a partially de-coppered eluate was studied. This scheme allows the use of acid formed in the process of copper electro-winning. The effect of concentrations of NH4Cl and NH4OH on the sorption of copper was studied. It was shown that, with an increase in the concentration of NH4Cl to 100 g/dm3, the capacity of the ion exchanger decreases by 10.42%. Thus, the ion exchanger Lewatit MonoPlus TP 207 effectively absorbs copper even at high salt background. A combined sorption-electrochemical technology has been proposed for treatment of rinse waters. The proposed technology will reduce consumption of fresh water and ammonia for printed circuit boards washing and extract copper in the form of elemental metal.
The application of chromium carbides in the composition of a powder flux-cored wire mixture for applying abrasion-resistant coatings is considered. It is shown, that when using chromium carbide in the charge of the electrode wire during surfacing, the reinforcement of the weld metal is not achieved. The use of chromium carbide instead of ferrochrome changes the structure of the wire and deposited metal, which increases the hardness of the coating.
Keywords:
surfacing, chromium carbides, abrasive wear, surfacing material, reinforcement.
aspankratov@bmstu.ru
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