The magnetic properties of monodisperse FeO-Fe3O4 nanoparticles with different mean sizes and volume fractions of FeO synthesized via decomposition of iron oleate were correlated to their crystallographic and phase compositional features by exploiting high resolution transmission electron microscopy, X-ray diffraction, Mössbauer spectroscopy and field and zero field cooled magnetization measurements. A model describing the phase transformation from a pure Fe3O4 phase to a mixture of Fe3O4, FeO and interfacial FeO-Fe3O4 phases as the particle size increases was established. The reduced magnetic moment in FeO-Fe3O4 nanoparticles was attributed to the presence of differently oriented Fe3O4 crystalline domains in the outer layers and paramagnetic FeO phase. The exchange bias energy, dominating magnetization reversal mechanism and superparamagnetic blocking temperature in FeO-Fe3O4 nanoparticles depend strongly on the relative volume fractions of FeO and the interfacial phase.

The quantitative measurement of the magnetization of individual magnetic nanoparticles (MNPs) using magnetic force microscopy (MFM) is described. Quantitative measurement is realized by calibration of the MFM signal using an MNP reference sample with traceably determined magnetization. A resolution of the magnetic moment of the order of 10−18 A m2 under ambient conditions is demonstrated, which is presently limited by the tip's magnetic moment and the noise level of the instrument. The calibration scheme can be applied to practically any magnetic force microscope and tip, thus allowing a wide range of future applications, for example in nanomagnetism and biotechnology.

The need for diluted magnetic semiconductors has stimulated research on Mn-doped ZnO. However, the type of magnetic coupling (ferro/para) in ZnMnO remains an issue of debate. We have investigated the magnetic properties of Mn-doped ZnO layers grown by molecular beam epitaxy. Some samples showed a hysteresis with remnant magnetization on the order of 10−5emu, thus eventually suggesting ferromagnetism. We observed that the critical influence of the substrate substantially affects magnetic property measurements. This has to be taken into account in order to clearly confirm ferromagnetism. In our case, after subtraction of the substrate effect, there is no evidence of a ferromagnetic behavior for the ZnMnO samples.

We study the remanent domain configurations of rectangular permalloy antidot lattices over a range of lattice parameters. The influence of antidot diameter, antidot spacing, and the aspect ratio of the lattice on the remanent domain configuration are investigated by magnetic force microscopy and supported by micromagnetic simulations. In the remanent state, areas of cells with the same orientation of average magnetization form magnetic super domains separated by super domain walls (SDWs). Two types of SDWs are identified. The first type is characterized by low stray field energy, is linear, and expands over many lattice constants. In contrast the second type shows high stray field energy and is situated at kinks of low energy SDWs. Its width can vary from a minimum of two lattice cells up to several lattice constants, depending on the lattice parameters. The occurrence and structure of these two types of SDWs as function of lattice parameters are classified and discussed in terms of the interplay of stray field and exchange energy.PACS number(s): 75.60.Ch, 75.78.Cd, 68.37.Rt.

No abstract