Closed-form theoretical expressions are derived for the integrated absorption coefficient of various zerophonon single and double transitions in heteronuclear isotopic variants of hydrogen in condensed phase. Theoretical analysis predicts a different kind of double transition in the spectra of solid HD, HT, and DT, where the rotational energy of one molecule changes by three quanta and the rotational energy of another molecule simultaneously changes by at least three quanta. The expressions for double transitions given in this paper may, for example, be applied to double transitions involving para-H 2 -HD or ortho-D 2 -HD pairs.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.