In this work, experimental hydrate dissociation conditions
of methane
in the presence of 0.06, 0.10, and 0.20 mass fractions of methanol
and 0.10 and 0.25 mass fractions of ethane-1,2-diol in aqueous
solutions are reported. In addition, phase equilibria of a ternary
mixture of methane (0.9319 mole fraction) + ethane (0.0481 mole fraction) + propane (0.02 mole fraction) in the presence of 0.25 mass
fraction of ethane-1,2-diol aqueous solution is investigated. A high-pressure
equilibrium cell is used for measurement of hydrate dissociation conditions
in the temperature range of (265.4 to 282.0) K and pressure range
of (1.97 to 6.96) MPa. The experimental gas hydrate dissociation conditions
are modeled using the van der Waals and Platteeuw (vdW-P) solid
solution theory for dealing with the hydrate phase and the Valderrama–Patel–Teja
equation of state (VPT-EoS) along with the nondensity dependent (NDD)
mixing rules to account for the fluid phases. The obtained experimental
data are finally compared with selected experimental data from the
literature as well as the model predictions, and acceptable agreements are observed.
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