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We propose here a method witch analyze the behavior of Quasi-square open ring frequency selective surface (FSS) by using an approach based on the wave iterative concept procedure method (WCIP) coupled to Retrieval from Scattering Parameters method . The scattering parameters calculated by WCIP for a Quasi-square open ring FSS are used, in analytical formulas, to calculate directly observable effective constitutive parameters (relative electric permittivity εreff , magnetic permeability μreff and refractive index n ) of a frequency selective surface. Results of effective constitutive parameters for a Quasi-square open ring FSS structure are presented by Simulation using MATLAB program codes translating the implementation of the proposed approach.