Colorful clusters: Silver nanoclusters consisting of only a few atoms exhibit large chemical-environment-responsive shifts of their optical absorption and emission bands, that is, large solvatochromism (see picture). The photophysical characteristics and electrochemiluminescence of the Ag clusters give them remarkable advantages over larger nanoparticles in applications such as molecular sensing.
International audienceIn the domain of decision-support tools for the management of marine fish resources, considerable attention has been paid to the development of models explaining how fish stocks change over space and time. In most models, fishing effort is assumed to be exogenous and determined by factors such as management. Increasingly, there has been a call for bio-economic models to also account for the dynamics of fishing fleets, recognizing that fishers respond to changing environmental, institutional and economic conditions. A growing literature has sought to explicitly model the endogenous determinants of the capacity of fishing fleets, the intensity of its use and its temporal and spatial allocation across fishing opportunities. We review this literature, focusing on empirical applications of the behavioural models that have been put forward to explain and predict observed fleet dynamics. We find that although economic factors are usually included as a dominant driver in most studies, this is often based on the use of proxy variables for the key economic drivers, for which adequate data are lacking. Also, while many studies acknowledge that social and social-psychological factors play a significant role in explaining observed fishing behaviour, their inclusion in fishing fleet dynamic models is still very limited. Progress in this domain can only be achieved via the development of multidisciplinary research programmes focusing on applied quantitative analysis of the drivers of fishing fleet dynamics
ABSTRACT. It has been acknowledged that natural sciences alone cannot provide an adequate basis for the management of complex environmental problems. The scientific knowledge base has to be expanded in a more holistic direction by incorporating social and economic issues. As well, the multifaceted knowledge has to be summarized in a form that can support science-based decision making. This is, however, difficult. Interdisciplinary skills, practices, and methodologies are needed that enable the integration of knowledge from conceptually different disciplines. Through a focus on our research process, we analyzed how and what kind of interdisciplinarity between natural scientists, environmental economists, and social scientists grew from the need to better understand the complexity and uncertainty inherent to the Baltic salmon fisheries, and how divergent knowledge was integrated in a form that can support science-based decision making. The empirical findings suggest that interdisciplinarity is an extensive learning process that takes place on three levels: between individuals, between disciplines, and between types of knowledge. Such a learning process is facilitated by agreeing to a methodological epochè and by formulating a global question at the outset of a process.
Hot electron injection into aqueous electrolyte solutions from metal/insulator/metal/electrolyte and metal/insulator/electrolyte tunnel junctions is considered and the possibility of an electrochemical generation of hydrated electrons is discussed. The hot electron-induced UV electrochemiluminescence of (9-Ñuorenyl)methanol was used to demonstrate the presence of highly energetic transient species in aqueous solution at several metal/insulator/electrolyte hot electron tunnel emitters. These transient species cannot be produced electrochemically in fully aqueous solutions at any active metal electrodes. A detailed mechanism for the present electrochemiluminescence is suggested.
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