The land spreading of olive mill wastewater (OMW) derived from olive oil production can represent a suitable option to enrich and maintain agriculture soils under south Mediterranean climates. Therefore, OMW spreading field may represent a low cost contribution to crop fertilization and soil amendment. The main objective of this study was to investigate the long-term effects of raw OMW application on soil macronutrients and phenolic compounds dynamics. The results showed that regular application of three doses: 50, 100 and 200 m 3 •ha −1 of OMW for nine successive years increased the soil electrical conductivity significantly (p ≤ 0.05%) with the increase of OMW rates at the depth 0-20 cm. The pH variations were not detected after ten months of the spreading date. Furthermore, soil sodium adsorption ratio (SAR) and exchangeable sodium percentage (ESP) values were substantially affected by OMW salinity. The soil organic matter (SOM) increased from 0.068% observed for the control sample to 0.2%, 0.34% and 0.48%, respectively, with the increase of OMW rate in the top layer (0-20 cm). The potassium, phosphorus and nitrogen increased gradually with the OMW application dose. The Ca 2+ contents on soil decreased with the spreading of OMW rate, as referred to control. In addition, the phenolic compounds variations were not proportional to doses applied and its levels remained high as compared with the control essentially on top layers (0-40 cm). This practice should be beneficial to organic farming and is an alternative solution to direct spreading of raw OMW on soil.
Landfill leachates (LFL) collected from Sfax (Tunisia) discharge area are characterized by high chemical oxygen demand (COD), ammonium and salts contents. They constitute a source of phytotoxicity and pollution for ground water and surface water resources which requires an adequate treatment process. To evaluate the efficiency of the coagulation/flocculation treatment, special attention was paid to the effect of pH, coagulant and flocculant doses. Then, effect of zero valent iron was also studied alone and in combination with coagulation/flocculation pretreatment. Our results indicate high removal efficiencies by coagulation/flocculation (46% COD and 63% turbidity) and Fenton process (48% COD and 76% turbidity). The combined application of coagulation/flocculation and Fenton revealed higher COD removal (62%) and turbidity reduction (90%). These results showed the applicability of this combined treatment method for the degradation of organic compounds and reduction of the treated leachate toxicity.
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