The potential habitability of Europa’s subsurface ocean depends on its chemical composition, which may be reflected in that of Europa’s geologically young surface. Investigations using Galileo Near-Infrared Mapping Spectrometer data led to the prevailing view that Europa’s endogenous units are rich in sulfate salts. However, recent ground-based infrared observations have suggested that, while regions experiencing sulfur radiolysis may contain sulfate salts, Europa’s more pristine endogenous material may reflect a chloride-dominated composition. Chlorides have no identifying spectral features at infrared wavelengths, but develop distinct visible-wavelength absorptions under irradiation, like that experienced on the surface of Europa. Using spectra obtained with the Hubble Space Telescope, we present the detection of a 450-nm absorption indicative of irradiated sodium chloride on the surface. The feature correlates with geologically disrupted chaos terrain, suggesting an interior source. The presence of endogenous sodium chloride on the surface of Europa has important implications for our understanding of its subsurface chemistry.

We present four daytime thermal images of Europa taken with the Atacama Large Millimeter Array. Together, these images comprise the first spatially resolved thermal data set with complete coverage of Europa's surface. The resulting brightness temperatures correspond to a frequency of 233 GHz (1.3 mm) and a typical linear resolution of roughly 200 km. At this resolution, the images capture spatially localized thermal variations on the scale of geologic and compositional units. We use a global thermal model of Europa to simulate the ALMA observations in order to investigate the thermal structure visible in the data. Comparisons between the data and model images suggest that the large-scale daytime thermal structure on Europa largely results from bolometric albedo variations across the surface. Using bolometric albedos extrapolated from Voyager measurements, a homogenous model reproduces these patterns well, but localized discrepancies exist. These discrepancies can be largely explained by spatial inhomogeneity of the surface thermal properties. Thus, we use the four ALMA images to create maps of the surface thermal inertia and emissivity at our ALMA wavelength. From these maps, we identify a region of either particularly high thermal inertia or low emissivity near 90°west and 23°north, which appears anomalously cold in two of our images.

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We present thermal observations of Ganymede from the Atacama Large Millimeter Array (ALMA) in 2016–2019 at a spatial resolution of 300–900 km (0.″1–0.″2 angular resolution) and frequencies of 97.5, 233, and 343.5 GHz (wavelengths of 3, 1.3, and 0.87 mm); the observations collectively covered all Ganymede longitudes. We determine the global thermophysical properties using a thermal model that considers subsurface emission and depth- and temperature-dependent thermophysical and dielectric properties, in combination with a retrieval algorithm. The data are sensitive to emission from the upper ∼0.5 m of the surface, and we find a millimeter emissivity of 0.75–0.78 and (sub)surface porosities of 10%–40%, corresponding to effective thermal inertias of 400–800 J m−2 K−1 s−1/2. Combined with past infrared results, as well as modeling presented here of a previously unpublished night-time infrared observation from Galileo’s photopolarimeter–radiometer instrument, the multiwavelength constraints are consistent with a compaction profile whereby the porosity drops from ∼85% at the surface to at depth over a compaction length scale of tens of centimeters. We present maps of temperature residuals from the best-fit global models, which indicate localized variations in thermal surface properties at some (but not all) dark terrains and at impact craters, which appear 5–8 K colder than the model. Equatorial regions are warmer than predicted by the model, in particular near the centers of the leading and trailing hemispheres, while the midlatitudes (∼30°–60°) are generally colder than predicted; these trends are suggestive of an exogenic origin.

Recent visible-wavelength observations of Europa’s surface obtained with the Hubble Space Telescope (HST) revealed the presence of an absorption feature near 450 nm that appears spatially correlated with leading-hemisphere chaos terrain. This feature was interpreted to reflect the presence of irradiated sodium chloride ultimately sourced from the interior. Here, we use ultraviolet spectra also collected with the HST to detect an additional previously unseen absorption near 230 nm, which spatially correlates with the 450 nm feature and with the same leading-hemisphere chaos terrain. We find that the new ultraviolet feature is also well matched by irradiated sodium chloride at Europa-like conditions. Such confirmation of sodium chloride within geologically young regions has important implications for Europa’s subsurface composition.