ABSTRACT:The graft copolymerization of glycidylmethacrylate (GMA) onto modified nylon-6 fibers containing polydiallyldimethylammonium chloride (PDADMAC) groups in the presence of (Cu 2ϩ -K 2 S 2 O 8 ) as a redox initiating system was carried out, with very high extent and almost without homopolymer formation. The mechanism of the graft polymerization induced by this system was suggested. The rate of grafting was determined by varying the monomer, K 2 S 2 O 8 , and cupric ion concentrations as well as the amount of PDAD-MAC. The kinetic investigation revealed that the rate of grafting (Rp) of GMA onto modified nylon-6 fibers is proportional to [GMA] . The overall activation energy was 134.7 kJ/mol. The fine structure and thermal properties of the grafted nylon-6 fibers were investigated.

Viscose dyeing is one of the major pollutants of water due to the large amount of salt in the dyeing effluent. This study paves the way for improving environmentally sustainable wool waste and highlights a promising invaluable application through salt-free viscose dyeing. The keratin hydrolysate (KH) was obtained using microwave (MW) alkaline hydrolysis then applied on the viscose fabric in the finishing bath formulation using the pad-cure technique. The rheology of the hydrolyzed wool fibers and the amino acids composition using high-performance liquid chromatograph (HPLC) was estimated; furthermore, the fourier transform infrared spectroscopy (FTIR) of freeze-drying keratin hydrolysate was evaluated. Microwave-assisted keratin hydrolysis leads to the breakdown of peptide bonds and the release of low molecular weight proteins and peptides. The color strength (K/S) of the dyed post-finished viscose fabric increased 75% compared with that dyed by conventional technique. FTIR, scanning electron microscopy (SEM) and energy disperse x-ray spectroscopy (EDX) demonstrated and confirmed the effective finishing of keratin hydrolysate. The tensile strength and elongation of viscose fabric did not change after finishing with KH, while the air permeability improved and the light fastness properties for the modified viscose fabrics.

This article introduce a novel, convenient and efficient finishing approach for the creation of quaternary ammonium groups (QAGs) into polyamide-6 (PA-6) macromolecules via polymerization of vinyl monomer is named methacryloyloxyethyl trimethyl ammonium chloride (MAETAC). The graft copolymerization reaction proceeds in the presence of nano-metal oxides TiO2, ZnO and its hybrid mixture. The finishing method of PA-6 fabrics was carried out by using pad-dry-cure technique in presence K2S2O8 as initiator. The reaction mechanism was suggested. The surface topography was studied using Scan Electron Microscope (SEM) and Energy dispersive X-Ray (EDX). Evidence the chemical bonding between poly (MAETAC) and amide groups as well as the ionic interaction between nanoparticles (NPs) and carboxylic end groups in the chemical structure of the PA-6 fabrics were confirmed by FT-IR. The antimicrobial activity of the finished fabrics were evaluated against Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, and Candida albicans. The achieved antimicrobial functions on the PA-6 fabrics are durable in repeated laundering processes. Even after laundering five times the PA-6 fabrics treated with QAs/Ti NPs could still provide 32%, 80.7%, 22.6%, and 60.5%, while PA fabrics treated with QAs/Zn or QAs/(Ti+Zn) showed excellent antimicrobial activity against Staphylococcus aureus, E. coli, P. aeruginosa, and C. albicans before laundering, respectively. Also, it has been found that, PA-6 fabrics finished with the suggested method even after five washing cycles, displayed excellent ultraviolet protection effectiveness. The results of mechanical properties showed that this finishing approach had not destructive effect on the physical properties of the fabrics.