In the above article, the dataset code number PASS00296 for the mass spectrometry data of the SFB-YTHDC1 tandem-affinity purification on peptideatlas.org was incorrect. The authors regret this error. It has now been replaced with the correct dataset code number, PASS00835, in the online version.
Highly efficient nanoparticle-on-metallic-mirror (NPOM) systems with a large gap size exhibiting good plasmonic enhancement are desirable for numerous practical applications. Careful, explicit design optimization strategies are required for preparing NPOMs,...
Detecting trace amounts of explosives to ensure personal safety is important, and this is possible by using laser-based spectroscopy techniques. We performed surface-enhanced Raman scattering (SERS) using plasmonic nanogap substrates for the solution phase detection of some nitro-based compounds, taking advantage of the hot spot at the nanogap. An excitation wavelength of 785 nm with an incident power of as low as ≈0.1 mW was used to excite the nanogap substrates. Since both RDX and PETN cannot be dissolved in water, acetone was used as a solvent. TNT was dissolved in water as well as in hexane. The main SERS peaks of TNT, RDX, and PETN were clearly observed down to the order of picomolar concentration. The variations in SERS spectra observed from different explosives can be useful in distinguishing and identifying different nitro-based compounds. This result indicates that our nanogap substrates offer an effective approach for explosives identification.
Transition metal based layered double hydroxides (TMLDHs) are potential candidates for supercapacitors; however, their structural staking often limits their energy density, one of the major pending obstacles in the sector. Simple, fast, and safe modification strategies such as exfoliation of jammed layers into single sheets can be a viable option to overcome those challenges. This work reports fabrication of an ultrathin nanosheets from bulk TMLDHs using superficial non-thermal Arplasma exfoliation strategy. Electrochemical characterizations have confirmed that capacitive performance of pristine NiCoO x nanosheets has improved because of Ar-plasma induced exfoliation. A remarkable of 5.7 F cm À 2 areal capacitance was achieved at a current density of 5 mA cm À 2 for ultrathin Ar-NiCoO x nanosheets. The material also exhibited excellent cyclic stability with over 88 % capacitance retention after 5000 cycles. The electrode material assembled into symmetric supercapacitor device delivering an energy density of 85.9 μWh cm À 2 at a power density of 500 μW cm À 2 .The higher supercapacitive performance is attributed to increased electrochemical surface area and improved capability of electron and ion transport induced by Ar-plasma exfoliation, demonstrating an opportunity for further use of TMLDHs in the energy conversion and storage sector.
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