This study investigates the efficacy of acid activated coconut husk (CHA) for the removal of rhodamine-B (Rh-B) dye from aqueous solutions. The CHA prepared was characterized using various techniques: SEM, FTIR EDX, Boehm titration and pH pzc , respectively. The effects of different operational parameters including initial concentration, contact time and solution temperatures were examined. Kinetic data for Rh-B dye adsorption onto CHA fitted best to pseudo-second-order kinetic model considering the correlation regression (R 2 ) and the sum of squares of error values. Adsorption data were fitted to Langmuir, Freundlich, Dubinin-Radushkevich and Temkin isotherm models. Langmuir isotherm was the most fitted among all the models used with maximum monolayer sorption capacity of 1666.67 mg g −1 and the highest regression value of 0.99 indicating that CHA has greater affinity for Rh-B dye adsorption due to increased pore development via acid activation. Thermodynamic studies revealed an endothermic adsorption process with the ΔH 0 value of 62.77 kJ mol −1 . Spontaneity was ascertained based on the negative values of ΔG o (ranging from − 26.38 kJ mol −1 to − 20.93 kJ mol −1 ). The positive value of ΔS 0 (0.276 kJ mol −1 K −1 ) suggests increased randomness that exists between CHA and Rh-B dye. Cost analysis results revealed that CHA is six times cheaper than commercial activated carbon (CAC), providing a savings of 217 US$ kg −1 . CHA adsorbent was found to be suitable for Rh-B dye removal from aqueous solution.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.