This study demonstrates the potential of different cinnamate esters, namely methyl trans‐cinnamate (MC), isobutyl cinnamate (IBC), allyl cinnamate (AC), and ethyl cinnamate (EC), as environmentally friendly plasticizers for polylactide (PLA). Plasticized PLA formulations with a constant nominal wt% of 20 of each plasticizer are compounded in a twin‐screw co‐rotating extruder and subsequently processed by injection molding. The results show exceptional plasticization efficiency of AC with an increase in elongation at break from 3.9% (neat PLA), up to 339.4% and a remarkable increase in impact strength, thus showing great potential to overcome the main drawback related to PLA intrinsic brittleness. The incorporation of cinnamates in a PLA matrix leads to a decrease in Tg from 61.7 °C down to 36.1 °C for the plasticized PLA formulation containing 20 wt% AC. Thermogravimetry analysis reveals that a slight plasticizer loss occurs during processing, as it happens with other monomeric plasticizers, but this phenomenon does not limit their plasticization efficiency. Therefore, the results obtained in this study confirm the suitability of a new family of organic compounds derived from the esterification of cinnamic acid as green plasticizers for PLA with improved toughness, with comparable, or even superior, ductile properties of typical plasticizers for PLA.
Metal containers are the most commonly used packaging worldwide in both the food processing industry. Usually, the production processes involved in the canning industry include multi-step transformations that take large aluminum or steel coils and make them into two or three-piece cans. During this process, these parts are sprayed to obtain a better surface for the contents; however, this spray produces volatile organic compounds (VOC). This paper presents a new and environmentally friendly can manufacturing method, which uses a novel pre-laminated two-layer polymer steel. As experimentally proven, this innovative polymer-coated steel successfully withstands every manufacturing requirement. The specimens were tested in an ironing simulator, measuring roughness, and friction coefficients. The development of an upper bound ironing model, along with a supporting neural network, allows an insight into the design of new materials for can manufacturing.
Abstract. The last decades llave been characterized by a fast evolution of cars. This work shows the evolution of vehicle weight. It sI10ws the response of car manufacturers using new materials and production meUlods that allow lighter vehicles with lower consumption, cheaper and with 1000ver influence 011 the greenhouse effect. One of the materials which means a most interesting change is the TWIP steel. This material is characterized by its high strengUl, his exceptional strain and excellent formabílily as weH as lower energy consumption in Uleir manufacture. TWIP steel are changing to\vards cheaper compositions and higber perfonl1ance, and it's going to be great influence in the vehicle weight reduction in tbe next years.
Bamboo fiber is one of the strongest natural fibers with high strength‐to‐weight and stiffness‐to‐weight ratios and can be used economically for manufacturing fiber‐reinforced composites. In this paper, bamboo fabric‐reinforced epoxy composite is manufactured and its tribological properties for load‐bearing applications are investigated. Sliding wear tests are conducted using a linear reciprocating tribometer and the effect of dry and lubricated contact conditions, applied load, sliding speed, temperature, and woven fabric direction on the coefficient of friction and wear rate are investigated. A scanning electron microscope is used to define the wear mechanisms at room and elevated temperatures. It is observed that the fabric orientation influences the mechanical and tribological performances of the composite material. Wear rate increases at higher loads and working temperatures; however, the effect of sliding speed is not remarkable, especially under lubricated contact conditions. The results present in this paper can be used for designing bamboo‐reinforced epoxy composites for load‐bearing applications, under different working conditions.
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