All-inkjet printed large area organic solar cells deposited from environmentally friendly solvents are demonstrated for the first time.

No abstract

When alkanethiolate self-assembled monolayers on Au{111} are exchanged with alkaneselenols from solution, replacement of thiolates by selenols is rapid and complete, and is well described by perimeter-dependent island growth kinetics. The monolayer structures change as selenolate coverage increases, from being epitaxial and consistent with the initial thiolate structure to being characteristic of selenolate monolayer structures. At room temperature and at positive sample bias in scanning tunneling microscopy, the selenolate–gold attachment is labile, and molecules exchange positions with neighboring thiolates. The scanning tunneling microscope probe can be used to induce these place-exchange reactions.

A B S T R A C TA commonly used strategy in the fabrication of organic electronics involves the use of orthogonal solvents, i.e. the alternating use of organic solvents and water for the application of consecutive layers to prevent dissolution of previous layers. This strategy therefore requires the deposition of sequential layers with a large mismatch in surface energy. In case of organic photovoltaics (OPV) a particularly challenging deposition is that of the aqueous Poly(3,4-ethylenedioxythiophene) Polystyrene sulfonate (PEDOT:PSS) on the hydrophobic Poly(3hexylthiophene-2,5-diyl/Phenyl-C61-butyric acid methyl ester (P3HT/PCBM) layer. The mismatch in surface energy causes dewetting and inhomogeneous layer formation. In inkjet printing individually placed droplets should spread sufficiently far to form a homogeneous closed layer before the solvents in the droplet evaporate. A formulation for the aqueous PEDOT:PSS layer has been developed in which the combination of solvents and surfactants is essential for achieving a homogenous layer on the timescales needed for inkjet printing. Homogenous layers of PEDOT:PSS on P3HT/PCBM were achieved for layer thicknesses from 400 nm to 50 nm. The efficiency of the OPV's fabricated with the new formulation were comparable with reference devices, where evaporated molybdenum oxide (MoO x ) was used as a topelectrode. This shows that by the addition of solvents and surfactants a hydrophilic solution can be inkjet printed successfully to form homogenous layers on hydrophobic surfaces and achieve good efficiencies in an inverted organic solar cell.

We describe and characterise a novel method of producing tuneable surface topography in fluorinated elastomers using a modified photo-embossing process.