The supply of drinking water to the population is an important challenge facing humanity, since both surface and underground sources present a great variability of water storage with respect to space and time. This problem is further aggravated in arid and semi-arid areas where rainfall is low and torrential, which makes groundwater the main source of supply; therefore, it is necessary to carry out studies that allow evaluating the evolution of the quantity and quality of water. This study addresses the behavior of groundwater in a semi-arid region, considering the theory of flow systems to identify movement as well as water quality, es determined by a water quality index (WQI), calculated considering arsenic and fluorine. In addition, a quality irrigation classification is used, employing the norms in accordance with international standards and the Mexican Norm, which allows for a comparison. Local, regional, intermediate and mixed flow systems are identified, and the evolution of cations and anions in addition to temperature is examined. It is observed that the drinking water quality index classifies them as excellent in most of the monitored wells (<50), but with a negative evolution. Regarding irrigation, most of the water samples are classified without restriction for the establishment of any type II crop (C2S1) and with restrictions for horticultural crops. It is observed that arsenic had values between 0.49 and 61.40 (µg/L) in 2005, while in 2015 they were between 0.10 and 241.30 (µg/L). In addition, fluoride presented values between 0.00 and 2.6 (mg/L) in 2005, while in 2015 they were between 0.28 and 5.40 (mg/L). The correlations between arsenic and fluorine are noted as well as WQI and SAR. A finding in this research was to include arsenic and fluorine in the calculation of the WQI allowing a better interpretation of the quality of water for both human consumption and for agricultural use to based on this make the best decision to control any harmful effects for the population, in addition to identifying the appropriate purification treatment required to control pollutants. It is concluded that arsenic is an element of utmost importance when considering water quality, so it is necessary to examine its evolution and continue to monitor its levels constantly.

Hydrological cycle research requires a detailed analysis of the involved parameters to understand watershed behavior comprehensively. In recent decades, both Geographic Information Systems (GIS) and Digital Elevation Models (DEMs) were implemented and took a substantial role in watershed geomorphological parameterization; however, the variability of these instruments remains a challenge, together with high-resolution DEMs being unavailable, requiring digital processing to improve resolution. This research aims to merge DEMs and evaluate GIS geoprocessing algorithms to determine drainage networks and the geomorphological parametrization of a semiarid watershed. DEMs with resolutions of 1.5, 5, 12.5, and 30 m, the Jenson/Domingue (J/D) and Wang/Liu (W/L) fill algorithms; and D8, D, KRA, and MFD flow routing algorithms were used. One of the research findings proved that the divergences of the drainage networks are mainly attributed to filling algorithms and not flow routing algorithms; the shifts between the networks obtained in the processes reach horizontal distances up to 300 m. Since the water movement within the watershed depends on geomorphological characteristics, it is suggested that DEM-based hydrological studies specify both the resolution and the algorithms used in the parametrization to validate the rigidity of the research, improving estimate areas of high hydrological risk.

In arid and semiarid regions, groundwater becomes the main source to meet the drinking water needs of large cities, food production, and industrial activities. For this reason, necessary studies must be carried out to estimate its quantity and quality, always seeking sustainable management, thus avoiding social conflicts or a decrease in the productive activities of humanity. This research explains the behavior of groundwater quality concerning arsenic speciation and its relationship with fluoride. The average total arsenic concentration of 19.95 µg/L and 20.29 µg/L is reported for the study period from 2015 to 2020, respectively, according to the Mexican standard. If the population drinks water directly, it is exposed to possible damage to health. The predominant arsenic species is As (V), with 95% and As (III) with 5%, this finding will allow us to define in greater detail the type of remediation that is required to reduce the content of this element in the water. Regarding the relationship between arsenic and fluorine, very small Pearson correlation coefficients of the order of 0.3241 and 0.3186 were found. The estimation of the space–time variation made it possible to identify the areas with the highest concentration of arsenic and fluorine, allowing the definition of the operating policies of these wells, thereby protecting the health of the inhabitants who consume this water.

Groundwater is the main source of freshwater available for human beings and is generally extracted through wells. The objective of this work was to schematize the groundwater flow systems within the Calera Aquifer through 3D geostatistical estimations of hydraulic head and physico-chemical parameters and the integration of hydrogeological features. The evolution of groundwater during its circulation in the subsoil can be done by identifying different types of flow (local, intermediate, regional, or mixed). Two main approaches have been proposed for the identification of flow systems: explaining the evolution of physico-chemical parameters of water through its interaction with the geologic medium, and using cluster analysis; however, these approaches usually do not consider simultaneously the 3D distribution of hydraulic head, water quality parameters, and the geological media that can be useful to delineate converging flow systems with a differentiated origin. In this paper, the determination of groundwater flow systems within the Calera aquifer in Mexico is supported with 3D representations of these hydrogeological variables besides constructive data of the sampled well. For the case study, the convergence of different flow systems that are not identified through a single cluster analysis was actually noticed by the proposal done in this paper.