No abstract

Silicone-based polymers have been widely used for many applications, but their extremely low surface energies and the resulting poor adhesion have been the cause for continuous problems. Herein, a novel adhesion improvement technique using an interlocked finger structure is demonstrated, which enables up to 24.8 and 7.3-fold increases in adhesion compared to the untreated and conventional plasma-treated cases, respectively. The interlocked finger structure is fabricated by surface-confined dissolution and subsequent directional melt crystallization of a solvent. After removing the solvent crystals, porous surfaces are prepared from polyurethane, polyvinyl alcohol, and polystyrene, and these are used to fabricate interfaces of interlocked finger structures with polydimethylsiloxane. The improvement in adhesion strength linearly depends on the pore depth of the prepared surfaces. This novel technique of surface adhesion could improve the performance of polymers with intrinsically poor adhesion in future applications.

No abstract

Engineering the surface properties of a material without affecting its bulk properties is desirable for many applications, but it is often not readily achievable because it requires a complex series of processing steps. This study presents for the first time a simple and straightforward method that can convert regular flat polymer surfaces into various porous composite surfaces. The controlled dissolution of the polymer surface by a dispersion and subsequent melt crystallization allows for the successful embedding of dispersed inorganic or organic particles in the pore walls. The porous surface morphology is not significantly affected by the type of dispersed particle, but the contact and sliding angles and surface wettability are. Both superhydrophobic and oil/water separation surfaces can be conveniently fabricated from flat polymer surfaces. This novel and versatile technique could provide engineering freedom for the future development of various functional materials.