In the printing plate developing process, the offset printing developer undergoes changes, as well as enrichment by the various chemicals, i.e. metals, organic binders and photosensitive compounds. The objective of this study was to investigate the electrocoagulation/flotation (ECF) treatment efficiency for the removal of copper, turbidity and organic substances from the waste offset printing developer (WOPD). The effect of operational parameters, such as electrode materials, current density, interelectrode distance and operating time, was studied. Also, the response surface analysis was applied to evaluate the effect of main operational variables and to get a balanced removal efficiency of investigated WOPD parameters by ECF treatment. The removal efficiency increases significantly with the increasing of operating time and mainly increases with the increasing of current density. The obtained results show that the interelectrode distance and combinations of electrodes determine the removal efficiency of copper, turbidity and organic substances. Based on the obtained results, the optimized parameters for the ECF treatment removal of investigated WOPD parameters were identified as: Al(À)/Fe(+) electrode combination with interelectrode
Dissecting a human cadaver is an irreplaceable practice in general training of medical students. Cadavers in anatomy laboratories are usually preserved in formalin, an embalming fluid whose basic component is formaldehyde (FA). The aim of this study is to assess the cancer risk of employees and students that are exposed to FA based on the results of three monitoring campaigns, as well as to suggest permanent solutions to the problem of FA exposure based on the results obtained. Three sampling campaigns of formaldehyde concentration in indoor environments were conducted at five different locations at the Anatomy Department of the Faculty of Medicine with the purpose of assessing permanent employees’ and medical faculty first year students’ exposure to FA. Indoor air was continuously sampled during 8 h of laboratory work and analyzed in accordance with the NIOSH Method 3500. Exceeding of the 8 h time-weighted average (8 h TWA) values recommended by Occupational Safety and Health Administration (OSHA) of 0.75 ppm was recorded in 37% of the samples during the three-month monitoring campaign. Cancer risk assessment levels for permanent employees were in the range from 6.43 × 10−3 to 8.77 × 10−4, while the cancer risk assessment levels for students ranged from 8.94 × 10−7 to 1.83 × 10−6. The results of the research show that cancer risk assessment for employees is several thousand times higher than the limit recommended by the EPA (10−6) and point to the importance of reducing exposure to formaldehyde through the reconstruction of the existing ventilation system, continual monitoring, the use of formaldehyde-free products, and plastination of anatomical specimens.
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