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Ring-over-ring slippage and ring-through-ring penetration are important processes in the construction of ring-in-ring multiple interlocked architectures. We have successfully observed “ring-over-ring deslipping” on the rotaxane axle by exploiting the dynamic covalent nature of imine bonds in imine-bridged heterorotaxanes R1 and R2 with two macrocycles of different ring sizes on the axle. When the imine bridges of R1 were cleaved, a hydrolyzed hetero[4]rotaxane [4]R1′ was formed as an intermediate under dynamic equilibrium, and the larger 38-membered macrocycle M was deslipped over the 24-membered ring (24C8 or DB24C8) to dissociate into a [3]rotaxane [3]R3 and a macrocycle M. The time dependent NMR measurement and the determined thermodynamic parameters revealed that the rate-limiting step of the deslipping process was attributed to steric hindrance between two rings and reduced mobility of M due to proximity to the crown ether, which was bound to the anilinium on the axle molecule.

Sea level rise and an increase in typhoon intensity are two of the expected consequences from future climate change. In the present work a methodology to change the intensity of tropical cyclones in Japan was developed, which can be used to assess the inundation risk to different areas of the country. An example of how this would affect one of the worst typhoons to hit the Tokyo Bay area in the 20th century was thus developed, highlighting the considerable dangers associated with this event, and how current sea defences could be under danger of failing by the end of the 21st century.

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