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The present investigation focuses on the separation of phenanthrene (a polyaromatic hydrocarbon) from n-tetradecane (model diesel composition) via pervaporation using a fabricated aromatic polyimide membrane. The experiments demonstrate preferential permeation of the polyaromatic for all films within the studied experimental range. The influence of operating temperature, membrane pretreatment time, membrane composition, and membrane thickness on the pervaporative performance were investigated. Statistical software Design Expert 7.1.4 was used to derive the regression equation describing the effect of the above mentioned factors on the pervaporation separation index. These factors are optimized using response surface methodology. The highest value of pervaporation separation index obtained is 1.5277 kg m 22 h 21 and the corresponding optimized condition is: operating temperature 493 K, pretreatment time 16.55 h with a membrane composition of 2.76 wt% of phenanthrene in polyamic acid and thickness 53.22 mm.

Removal of polyaromatics from diesel is important to meet automobile emission specifications. According to Worldwide Fuel Charter, the maximum allowable concentration of polyaromatic hydrocarbons (PAHs) in automotive diesel should be less than 2% vol (max). An aromatic polyimide membrane was fabricated by solution casting a mixture of polyamic acid, N,N‐dimethylacetamide and phenanthrene. This membrane was utilized for the separation of a multicomponent mixture consisting of acenaphthene and 2‐methyl naphthalene (PAHs) in toluene and n‐tetradecane, chosen as model diesel composition via pervaporation. The prepared membrane was characterized by mechanical strength testing, SEM and TGA‐DTA study. The influence of varying downstream pressure, feed composition, and operating temperature on the pervaporative separation performance in terms of combined permeation flux of the PAHs was investigated. A central composite experimental design along with response surface methodology was conducted to optimize these process factors for maximizing the combined permeation flux. The maximum value of combined permeation flux obtained was 0.071 kg m−2 h−1. Hence, it can be concluded that the novel membrane fabricated using a simple and relatively inexpensive method has good potentiality for pervaporative removal of PAHs from the chosen system. © 2018 American Institute of Chemical Engineers Environ Prog, 37: 1901–1907, 2018

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