We show that, in conserved-mass transport processes, the steady-state distribution of mass in a subsystem is uniquely determined from the functional dependence of variance of the subsystem mass on its mean, provided that the joint mass distribution of subsystems is factorized in the thermodynamic limit. The factorization condition is not too restrictive as it would hold in systems with short-ranged spatial correlations. To demonstrate the result, we revisit a broad class of mass transport models and its generic variants, and show that the variance of the subsystem mass in these models is proportional to the square of its mean. This particular functional form of the variance constrains the subsystem mass distribution to be a gamma distribution irrespective of the dynamical rules.
We ask what happens when two nonequilibrium systems in steady state are kept in contact and allowed to exchange a quantity, say mass, which is conserved in the combined system. Will the systems eventually evolve to a new stationary state where a certain intensive thermodynamic variable, like equilibrium chemical potential, equalizes following the zeroth law of thermodynamics and, if so, under what conditions is it possible? We argue that an equilibriumlike thermodynamic structure can be extended to nonequilibrium steady states having short-ranged spatial correlations, provided that the systems interact weakly to exchange mass with rates satisfying a balance condition-reminiscent of a detailed balance condition in equilibrium. The short-ranged correlations would lead to subsystem factorization on a coarse-grained level and the balance condition ensures both equalization of an intensive thermodynamic variable as well as ensemble equivalence, which are crucial for construction of a well-defined nonequilibrium thermodynamics. This proposition is proved and demonstrated in various conserved-mass transport processes having nonzero spatial correlations.
We exactly calculate two-point spatial correlation functions in steady state in a broad class of conserved-mass transport processes, which are governed by chipping, diffusion, and coalescence of masses. We find that the spatial correlations are in general short-ranged and, consequently, on a large scale, these transport processes possess a remarkable thermodynamic structure in the steady state. That is, the processes have an equilibrium-like additivity property and, consequently, a fluctuation-response relation, which help us to obtain subsystem mass distributions in the limit of subsystem size large.
While a large number of studies have focused on the nonequilibrium dynamics of a system when it is quenched instantaneously from a disordered phase to an ordered phase, such dynamics have been relatively less explored when the quench occurs at a finite rate. Here, we study the slow quench dynamics in two paradigmatic models of classical statistical mechanics, a one-dimensional kinetic Ising model and a mean-field zero-range process, when the system is annealed slowly to the critical point. Starting from the time evolution equations for the spin–spin correlation function in the Ising model and the mass distribution in the zero-range process, we derive the Kibble–Zurek scaling laws. We then test a recent proposal that critical coarsening, which is ignored in the Kibble–Zurek argument, plays a role in the nonequilibrium dynamics close to the critical point. We find that the defect density in the Ising model and a scaled mass distribution in the zero-range process decay linearly to their respective values at the critical point with the time remaining until the end of the quench provided the final quench point is approached sufficiently fast, and sublinearly otherwise. As the linear scaling for the approach to the critical point also holds when a system following an instantaneous quench is allowed to coarsen for a finite time interval, we conclude that critical coarsening captures the scaling behavior in the vicinity of the critical point if the annealing is not too slow.
We show that an equilibriumlike additivity property can remarkably lead to power-law distributions observed frequently in a wide class of out-of-equilibrium systems. The additivity property can determine the full scaling form of the distribution functions and the associated exponents. The asymptotic behavior of these distributions is solely governed by branch-cut singularity in the variance of subsystem mass. To substantiate these claims, we explicitly calculate, using the additivity property, subsystem mass distributions in a wide class of previously studied mass aggregation models as well as in their variants. These results could help in the thermodynamic characterization of nonequilibrium critical phenomena.
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