Shallow trench isolation (STI) technology with a poly-Si buffer layer at the trench sidewall has been studied. At the densification temperature of 950 • C, for the samples without using a poly-Si buffer layer, the resulting junction shows a leakage of about 700 nA cm −2 for a diode area of 100 × 100 µm 2 , primarily due to large peripheral junction leakage. The large leakage is ascribed to the defect generation caused by a thermally induced stress near the trench sidewall. The usage of a poly-Si buffer layer in the trench sidewall is found to significantly improve the junction characteristics. As a result, when a 40 nm poly-Si buffer layer is sandwiched between the Si substrate and the trench-fill silicon oxide, the resultant junctions show a leakage of only about 8 nA cm −2 . This result may reflect the considerably reduced thermally induced stress near the trench sidewall. Furthermore, at the densification temperature of 1100 • C, the usage of a poly-Si buffer layer can help to achieve excellent junctions with a leakage smaller than 5 nA cm −2 for a diode area of 100 × 100 µm 2 .
Double Spacer local oxidation of silicon (LOCOS) with shallow recess of silicon (DS-LOCOS) is described. The process has two spacers, a thin nitride spacer and a medium temperature chemical vapor deposition (CVD) oxide spacer. The process does not have intentional silicon recess etching step but achieves the shallow recess of silicon through nitride overetchings. It has been found that the key processes of the DS-LOCOS are both isolation etching and spacer etching, which critically affect 2ΔW and V t roll-off behaviors of active transistor and junction characteristics. The DS-LOCOS achieves physical bird's beak length of below 0.03 µ m/side, field oxide volume ratio over 80%, and superior planar surface. The DS-LOCOS also gives no degradation in punchthrough voltage down to 0.20 µ m isolation spacing and in gate oxide reliability. These results show that the DS-LOCOS is a simple and promising isolation technology for sub-quarter micron design rule.
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