Phase-change materials (PCM) play off their advantages over conventional heat storage media when used within narrow temperature ranges. Many cooling and temperature buffering applications, such as cold storage and battery cooling, are operated within small temperature differences, and therefore, they are well-suited for the application of these promising materials. In this study, the storage capacities of different phase-change material emulsions are analysed under consideration of the phase transition behaviour and supercooling effect, which are caused by the submicron size scale of the PCM particles in the emulsion. For comparison reasons, the same formulation for the emulsions was used to emulsify 35 wt.% of different paraffins with different purities and melting temperatures between 16 and 40 °C. Enthalpy curves based on differential scanning calorimeter (DSC) measurements are used to calculate the storage capacities within the characteristic and defined temperatures. The enthalpy differences for the emulsions, including the first phase transition, are in a range between 69 and 96 kJ/kg within temperature differences between 6.5 and 10 K. This led to an increase of the storage capacity by a factor of 2–2.7 in comparison to water operated within the same temperature intervals. The study also shows that purer paraffins, which have a much higher enthalpy than blends, reveal, in some cases, a lower increase of the storage capacity in the comparison due to unfavourable crystallisation behaviour when emulsified. In a second analysis, the stability of emulsions was investigated by applying 100 thermal cycles with defined mechanical stress at the same time. An analysis of the viscosity, particle size and melting crystallisation behaviour was done by showing the changes in each property due to the cycling.

Abstract. The thermal flow in a FLATCON® -type CPV module is investigated theoretically and experimentally. For the simulation a model in the computational fluid dynamics (CFD) software SolidWorks Flow Simulation was established. In order to verify the simulation results the calculated and measured temperatures were compared assuming the same operating conditions (wind speed and direction, direct normal irradiance (DNI) and ambient temperature). Therefore, an experimental module was manufactured and equipped with temperature sensors at defined positions. In addition, the temperature distribution on the back plate of the module was displayed by infrared images. The simulated absolute temperature and the distribution compare well with an average deviation of only 3.3 K to the sensor measurements. Finally, the validated model was used to investigate the influence of the back plate material on the temperature distribution by replacing the glass material by aluminum. The simulation showed that it is important to consider heat dissipation by radiation when designing a CPV module.

Latent thermal energy storages (LTES) offer a high storage density within a narrow temperature range. Due to the typically low thermal conductivity of the applied phase change materials (PCM), the power of the storages is limited. To increase the power, an efficient heat exchanger with a large heat transfer surface and a higher thermal conductivity is needed. In this article, planar wire cloth heat exchangers are investigated to obtain these properties. They investigated the first time for LTES. Therefore, we developed a finite element method (FEM) model of the heat exchanger and validated it against the experimental characterization of a prototype LTES. As PCM, the commercially available paraffin RT35HC is used. The performance of the wire cloth is compared to tube bundle heat exchanger by a parametric study. The tube diameter, tube distance, wire diameter and heat exchanger distance were varied. In addition, aluminum and stainless steel were investigated as materials for the heat exchanger. In total, 654 variants were simulated. Compared to tube bundle heat exchanger with equal tube arrangement, the wire cloth can increase the mean thermal power by a factor of 4.20 but can also reduce the storage capacity by a minimum factor of 0.85. A Pareto frontier analysis shows that for a free arrangement of parallel tubes, the tube bundle and wire cloth heat exchanger reach similar performance and storage capacities.

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